东北大学学报(自然科学版) ›› 2022, Vol. 43 ›› Issue (5): 709-717.DOI: 10.12068/j.issn.1005-3026.2022.05.015

• 资源与土木工程 • 上一篇    下一篇

细粒滑石对孔雀石硫化浮选的影响

刘宇彤, 印万忠, 盛秋月, 姚金   

  1. (东北大学 资源与土木工程学院, 辽宁 沈阳110819)
  • 修回日期:2021-07-08 接受日期:2021-07-08 发布日期:2022-06-20
  • 通讯作者: 刘宇彤
  • 作者简介:刘宇彤(1997-),女,黑龙江哈尔滨人,东北大学硕士研究生; 印万忠(1970-),男,浙江临安人,东北大学教授,博士生导师.
  • 基金资助:
    国家自然科学基金资助项目(51874072,51974064); 中央高校基本科研业务费专项资金资助项目(N2101025).

Effect of Fine Talc on Sulfurized Flotation of Malachite

LIU Yu-tong, YIN Wan-zhong, SHENG Qiu-yue, YAO Jin   

  1. School of Resources & Civil Engineering, Northeastern University, Shenyang 110819, China.
  • Revised:2021-07-08 Accepted:2021-07-08 Published:2022-06-20
  • Contact: YIN Wan-zhong
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摘要: 通过浮选试验发现细粒滑石的加入降低了孔雀石的硫化浮选可浮性,细粒滑石含量越多,对孔雀石的可浮性影响越大;通过Zeta电位测试、吸附量测试、SEM-EDS分析和EDLVO理论计算研究分析了细粒滑石影响孔雀石硫化浮选的原因.结果表明:适量的Na2S在孔雀石矿物表面的吸附是其硫化-黄药浮选成功的关键,而细粒滑石会吸附罩盖在孔雀石矿物表面,且滑石矿物表面不会发生Na2S的吸附,因此,细粒滑石减弱了孔雀石矿物表面的硫化效果,使其可浮性降低.

关键词: 孔雀石;滑石;浮选;吸附罩盖;EDLVO理论

Abstract: It is found that the addition of fine-grained talc reduces the floatability of malachite on sulfurized flotation by flotation test, and the higher the content of fine-grained talc, the greater the influence on the floatability of malachite.Zeta potential measurements, adsorption tests, SEM-EDS test and EDLVO theory calculation illustrated the reason for the influence of fine-grained talc on sulfurized flotation of malachite. The results show that the adsorption of appropriate amount of Na2S on the surface of malachite is the key to the success of sulfidization-xanthate flotation. The fine-grained talc adsorbs on the surface of malachite, and the adsorption of Na2S doesn’t occur on the surface of talc. Therefore, the fine-grained talc weakens the effect of sulfidization on the surface of malachite and reduces the floatability of malachite.

Key words: malachite; talc; flotation; adsorption cover; EDLVO theory

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