微波改造沸石环境材料的表征与脱氮效果

doi:10.12068/j.issn.1005-3026.2015.01.028

东北大学学报:自然科学版 ›› 2015, Vol. 36 ›› Issue (1): 129-133.DOI: 10.12068/j.issn.1005-3026.2015.01.028

微波改造沸石环境材料的表征与脱氮效果

林海，杨苏，张文通，马麒钧

(北京科技大学土木与环境工程学院，北京100083)

收稿日期:2013-08-23 修回日期:2013-08-23 出版日期:2015-01-15 发布日期:2014-11-07
通讯作者: 林海
作者简介:林海(1966-)，男，四川南充人，北京科技大学教授.
基金资助:
国家自然科学基金资助项目(51174017).

Characterization and Denitriding Effect of Microwave Modified Zeolite Ecomaterials

LIN Hai， YANG Su， ZHANG Wen-tong， MA Qi-jun

School of Civil and Environmental Engineering， University of Science and Technology Beijing， Beijing 100083， China，

Received:2013-08-23 Revised:2013-08-23 Online:2015-01-15 Published:2014-11-07
Contact: LIN Hai
About author:-
Supported by:
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摘要/Abstract

摘要： 通过添加不同类型助剂对天然沸石进行微波改造制备环境材料，并研究其对再生水中氨氮的去除效果.研究发现，相同的改造条件下，不同助剂的微波沸石对氨氮的去除效果顺序为:乙酸钠微波沸石>NaCl微波沸石>SDS微波沸石>CTMAB微波沸石>单独微波沸石>原沸石.孔径测试结果显示微波沸石的总孔体积、孔径数量、比表面积均有所提高.通过SEM，XRD等手段对微波改造前后的沸石表征，微波改造过程中助剂的加入使沸石颗粒表面松散度有不同程度的提高，出现了更多的孔道，主衍射峰强度有所减弱，沸石吸附性能提高.

关键词: 沸石, 氨氮, 微波改造, 助剂, 再生水处理

Abstract: Ecomaterials were modified and prepared by adding different additives on natural zeolite with microwave， and the effect of the matrials on removal of ammonia nitrogen was investigated. The results showed that the removal effect of ammonia nitrogen in sequence under the same modification conditions is microwave-assisted zeolite with sodium acetate， microwave-assisted zeolite with NaCl， microwave-assisted zeolite with SDS， microwave-assisted zeolite with CTMAB， microwave-assisted zeolite and natural zeolite. The aperture， pore volume and BET surface area increased after microwave-assisted zeolite with additives. The results of surface characteristics of zeolite were modificated with microwave or without by SEM and XRD indicated that additives can improve particles surface loose degree of zeolite， and there are more channels， the main diffraction peak intensity weakened，adsorption performance of zeolite improved.

Key words: zeolite, ammonia nitrogen, microwave modification, additives, recycled water treatment

中图分类号:

X703.5

林海，杨苏，张文通，马麒钧. 微波改造沸石环境材料的表征与脱氮效果[J]. 东北大学学报:自然科学版, 2015, 36(1): 129-133.

LIN Hai， YANG Su， ZHANG Wen-tong， MA Qi-jun. Characterization and Denitriding Effect of Microwave Modified Zeolite Ecomaterials[J]. Journal of Northeastern University Natural Science, 2015, 36(1): 129-133.

参考文献

[1]Li L，Song H Y，Jing C.Removal of ammonia nitrogen in wastewater by microwave radiation［J］.Journal of Hazardous Materials，2009，16(1):1063-1068.
[2]林海，杨苏，霍汉鑫，等.氯化钠对改性沸石微波脱除氨氮效果的影响［J］.化工学报，2013，64(8):2989-2995.(Lin Hai，Yang Su，Huo Han-xin，et al.Effect of sodium chloride on microwave-assisted removal of ammonia nitrogen by natural zeolite［J］.Journal of Chemical Industry and Engineering，2013，64(8):2989-2995.)
[3]Wang Y，Kmiyaa Y，Okuhara T.Removal of low-concentration ammonia in water by ion-exchange using Na-mordenite［J］.Water Research，2007，41(4):269-276.
[4]董颖博，林海，霍汉鑫.改造对沸石基复合环境材料表面结构的影响及应用［J］.功能材料，2012，43(19):2608-2612.(Dong Ying-bo，Lin Hai，Huo Han-xin.Effects of modification on the surface structure and application of composite environmental materials based on zeolite［J］.Journal of Functional Materials，2012，43(19):2608-2612.)
[5]Zhou R F，Zhong S L，Lin X，et al.Synthesis of zeolite T by microwave and conventional heating［J］.Microporous and Mesoporous Materials，2009，124(1/2/3):117-122.
[6]Cheng X W，He Q P，Guo J.Studies on the hydrothermal stability of natural and modified STI zeolite［J］.Microporous and Mesoporous Materials，2012，149(1):10-15.
[7]孙同喜，郑萌璐，蒋轶锋，等.NaCl改性沸石对氨氮吸附性能的研究［J］.环境污染与防治，2010，32(10):46-50.(Sun Tong-xi，Zheng Meng-lu，Jiang Yi-feng，et al.Effect of NaCl modification on ammonia-nitrogen adsorption property of zeolite［J］.Environmental Pollution & Control，2010，32(10):46-50.)
[8]Lei L C，Li X J，Zhang X W.Ammonium removal from aqueous solutions using microwave-treated natural Chinese zeolite［J］.Separation and Purification Technology，2008，5(8):359-366.
[9]Bai G Y，Li T Y，Yang Y H.Microwave-assisted friedel-crafts acylation of indole with acetic anhydride over tungstophosphoric acid modified Hβ zeolite［J］.Catalysis Communications，2012，29:114-117.
[10]Lin H，Jiang L Y，Zhao Z Y.Adsorption materials of nitrate and phosphate removal in secondary effluent advanced treatment ［J］.Journal of University of Science and Technology Beijing，2009，31(5):551-556.一位数()
[10]二位数()

微波改造沸石环境材料的表征与脱氮效果

Characterization and Denitriding Effect of Microwave Modified Zeolite Ecomaterials

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