纳米SiC粉末对先驱体陶瓷增材性能的影响

doi:10.12068/j.issn.1005-3026.2021.05.005

东北大学学报（自然科学版） ›› 2021, Vol. 42 ›› Issue (5): 639-645.DOI: 10.12068/j.issn.1005-3026.2021.05.005

纳米SiC粉末对先驱体陶瓷增材性能的影响

王志永^1,2,3，赵宇辉^1,2,4，赵吉宾^1,2，葛春华⁵

(1. 中国科学院沈阳自动化研究所，辽宁沈阳110016; 2. 中国科学院机器人与智能制造创新研究院，辽宁沈阳110169; 3. 东北大学机械工程与自动化学院，辽宁沈阳110819; 4. 中国科学院大学，北京100049; 5. 辽宁大学化学院，辽宁沈阳110036)

修回日期:2020-07-27 接受日期:2020-07-27 发布日期:2021-05-20
通讯作者: 王志永
作者简介:王志永(1994-)，男，黑龙江五常人，东北大学硕士研究生；赵吉宾(1970-)，男，辽宁沈阳人，中国科学院沈阳自动化研究所研究员，博士生导师.
基金资助:
基金项目；(半空) 基金项目.国家重点研发计划项目(2018YFB1105802)；国家自然科学基金资助项目(51805526).

Effect of Nano-Sized SiC Powder Filler on Additive Manufactured Properties of Precursor-Derived Ceramics

WANG Zhi-yong^1,2,3， ZHAO Yu-hui^1,2,4， ZHAO Ji-bin^1,2， GE Chun-hua⁵

1. Shenyang Institute of Automation， Chinese Academy of Sciences， Shenyang 110016， China; 2. Institutes for Robotics and Intelligent Manufacturing， Chinese Academy of Sciences， Shenyang 110169， China; 3. School of Mechanical Engineering and Automation，Northeastern University， Shenyang 110819， China; 4. University of Chinese Academy of Sciences， Beijing 100049， China; 5. College of Chemistry， Liaoning University， Shenyang 110036， China.

Revised:2020-07-27 Accepted:2020-07-27 Published:2021-05-20
Contact: ZHAO Yu-hui
About author:-
Supported by:
-

摘要/Abstract

摘要： 为了减少先驱体陶瓷在高温裂解过程中裂纹及孔隙的产生，研究了惰性填料纳米SiC粉末对先驱体聚合物、先驱体陶瓷体积收缩率、陶瓷产率的影响.利用热重分析(TGA)、傅里叶转化红外线光谱(FT-IR)、X射线衍射(XRD)等检测手段进行性能分析和结构表征，采用排水法计算先驱体陶瓷体积收缩率.结果表明:先驱体陶瓷的体积收缩率随纳米SiC粉末质量分数的增加而减小，先驱体陶瓷产率随纳米SiC粉末质量分数的增加而增加，当其质量分数为3%时，体积收缩率最小，为73.47%，先驱体陶瓷产率最大，为26.42%;在高温裂解过程中，当升温速率为4℃/min时，先驱体陶瓷表面无明显裂纹且平整光滑.SiC粉末作为惰性填料具有减少先驱体陶瓷体积收缩，提高陶瓷产率的作用，且效果明显.

关键词: 先驱体陶瓷;增材制造;惰性填料;体积收缩;陶瓷产率

Abstract: In order to reduce the generation of cracks and pores during the pyrolysis process of precursor-derived ceramics， the effects of the inert filler of nano-sized SiC powders on the precursor polymer， precursor-derived ceramics volume shrinkage， ceramic yield were studied. The features of precursor-derived ceramics with different mass fractions of SiC filler were examined by TGA， FT-IR and XRD technologies， and the volume shrinkage of the ceramics was measured by drainage method. The results showed that with the increasing mass fraction of SiC powders， the volume shrinkage of the precursor-derived ceramics decreased， while the yield of the ceramics increased. When the mass fraction was 3%， the volume shrinkage rate of the ceramics was down to the minimum value of 73.47% and the yield was up to the maximum one of 26.42%. During the pyrolysis process， when the heating rate was 4℃/min， the surface of the precursor-derived ceramics was flat and smooth without evident cracks. Therefore， the inert filler of the nano-sized SiC powders has great effects on reducing the volume shrinkage of precursor-derived ceramics and increasing the ceramic yield.

Key words: precursor-derived ceramics; additive manufacturing; inert filler; volume shrinkage; ceramic yield

中图分类号:

TQ174.75

王志永，赵宇辉，赵吉宾，葛春华5. 纳米SiC粉末对先驱体陶瓷增材性能的影响[J]. 东北大学学报（自然科学版）, 2021, 42(5): 639-645.

WANG Zhi-yong， ZHAO Yu-hui， ZHAO Ji-bin， GE Chun-hua5. Effect of Nano-Sized SiC Powder Filler on Additive Manufactured Properties of Precursor-Derived Ceramics[J]. Journal of Northeastern University(Natural Science), 2021, 42(5): 639-645.

参考文献

[1]Luo S，Zheng L，Luo H，et，al.A ceramic coating on carbon steel and its superhydrophobicity［J］.Applied Surface Science，2019，486(30):371-375.
[2]Ma Q S，Xu T H.High-temperature evolution behavior of polymer-derived SiAlOC ceramics under inert atmosphere［J］.Journal of Alloys and Compounds，2017，723:17-20.
[3]马廉洁，左宇辰，周云光，等.氧化锆陶瓷车削刀具几何参数的多目标优化［J］.东北大学学报(自然科学版)，2020，41(8):1129-1134.(Ma Lian-jie，Zuo Yu-chen，Zhou Yun-guang，et al.Multi-objective optimization of tool geometry parameters in turning zirconia ceramics［J］.Journal of Northeastern University(Natural Science)，2020，41(8):1129-1134.)
[4]Feilden E，Glymond D，Saiz E，et al.High temperature strength of an ultra high temperature ceramic produced by additive manufacturing［J］.Ceramics International，2019，45(15):18210-18214.
[5]Lakhdar Y，Tuck C，Binner J.Additive manufacturing of advanced ceramic materials［J］.Progress in Materials Science，2021，116:100736.
[6]Moritz T，Maleksaeedi S.4-additive manufacturing of ceramic components［M］.London:Additive Manufacturing，Butterworth-Heinemann，2018:105-161.
[7]Zhou S X，Mei H，Chang P，et，al.Molecule editable 3D printed polymer-derived ceramics［J］.Coordination Chemistry Reviews，2020，422:213486.
[8]朱世步，张强，孟祥利，等.液态聚碳硅烷的固化及陶瓷化［J］.航天制造技术，2019(3):1-6，13.(Zhu Shi-bu，Zhang Qiang，Meng Xiang-li，et al.Curing and ceramization of a liquid polycarbonsilane precursor［J］.Aerospace Manufacturing Technology，2019(3):1-6，13.)
[9]甄霞丽.聚铝碳硅烷纤维在臭氧气氛中的交联动力学及中空SiC纤维形成机理［D］.上海:上海大学，2019.(Zhen Xia-li.Crosslinking kinetics of Polyalumi-nocarbosilane fiber in ozone atmosphere and the formation mechanism of hollaw SiC fiber［D］.Shanghai:Shanghai University，2019.)
[10]王浩，王金龙，苟燕子.先驱体转化法制备高性能碳化硼陶瓷材料研究进展［J］.无机材料学报，2017，32(8):785-791.(Wang Hao，Wang Jin-long，Gou Yan-zi，et al.Progress of advanced boron carbide ceramic materials prepared by precursor derived method［J］.Journal of Inorganic Materials，2017，32(8):785-791.)
[11]Chen S G，Gou Y Z，Wang H，et，al.Preparation and characterization of high-temperature resistant ZrC-ZrB₂ nanocomposite ceramics derived from single-source precursor［J］.Materials & Design，2017，117:257-264.
[12]Chen Z W，Li Z Y，Li J J，et al.3D printing of ceramics:a review［J］.Journal of the European Ceramic Society，2019，4(39):661-687.
[13]陈朝辉.先驱体转化陶瓷基复合材料［M］.北京:北京出版社，2011:15-19.(Chen Zhao-hui.Precursor transformed ceramic matrix composites［M］.Beijing:Beijing Publishing Group，2011:15-19.)
[14]Aurélio I L，Dorneles L S，May L G.Extended glaze firing on ceramics for hard machining:crack healing，residual stresses，optical and microstructural aspects［J］.Dental Materials，2017，33(2):226-240.
[15]Greil P.Advancements in polymer-filler derived ceramics［J］.Journal of the Korean Ceramic Society，2012，49(4):279-286.
[16]Brahmandam S，Raj R.Novel composites constituted from hafnia and a polymer-derived ceramic as an interface:phase for severe ultrahigh temperature applications［J］.Journal of the American Ceramic Society，2007，90(10):3171-3176.
[17]宋彩雨，王磊，张斌，等.降低光固化收缩的研究进展［J］.高分子材料科学与工程，2017，33(10):175-182.(Song Cai-yu，Wang Lei，Zhang bin，et al.Research progress on reducing shrinkage of UV curing［J］.Polymer Materials Science and Engineering，2017，33(10):175-182.)
[18]Bian H，Song Y Y，Liu D，et al.Joining of SiO₂ ceramic and TC₄ alloy by nanoparticles modified brazing filler metal［J］.Chinese Journal of Aeronautics，2020，33(1):383-390.
[19]Xu X B，Li P Y，Ge C H，et al.3D printing of complex-type SiOC ceramic derived from liquid photosensitive resin［J］.Chemistry，2019，4:1-9.
[20]张世鹏，铁生年.KH-570硅烷偶联剂表面改性微硅粉分散性研究［J］.人工晶体学报，2018，47(7):1396-1401.(Zhang Shi-peng，Tie Sheng-nian.Surface modification of silica fume dispersivity with silane coupling agent KH-570［J］.Journal of Synthetic Crystals，2018，47(7):1396-1401.)
[21]Ackerman W E，Buhimschi I A，Zhao G M，et al.819:N-of-1 pathway analysis of sibling placental transcriptomes in twin pregnancies complicated by preeclampsia (PE)［J］.American Journal of Obstetrics and Gynecology，2020，222(1):515-516.
[22]陈曼华，陈朝辉.聚碳硅烷先驱体交联后热处理对陶瓷转化的影响［J］.国防科技大学学报，2003(2):38-40.(Chen Man-hua，Chen Zhao-hui.Effects of heat-treatment following crosslinking of polycarbosilane on ceramic conversation［J］.Journal of National University of Defense Technology，2003(2):38-40.)
[23]Martnez-Crespiera S，Ionescu E，Kleebe H J，et al.Pressureless synthesis of fully dense and crack-free SiOC bulk ceramics via photo-crosslinking and pyrolysis of a polysiloxane［J］.Journal of the European Ceramic Society，2011，31(5):913-919.
[24]De Hazan Y，Penner D.SiC and SiOC ceramic articles produced by stereolithography of acrylate modified polycarbosilane systems［J］.Journal of the European Ceramic Society，2017，37(16):5205-5212.
[25]Johanna S，Paolo C.Digital light processing of ceramic components from polysiloxanes［J］.Journal of the European Ceramic Society，2018，38:57-66.
[26]徐天恒.聚硅氧烷转化SiOC陶瓷微观结构的演变与改性［D］.长沙:国防科学技术大学，2011.(Xu Tian-heng.Structure evolutions and modifications of SiOC ceramics derived from polysiloxane［D］.Changsha:National University of Defense Technology，2011.)
[27]Yuan Q，Chai Z F，Huang Z R，et al.New precursor of liquid and curable polysiloxane for highly cost-efficient SiOC-based composites［J］.Ceramics International，2019，45(6):7044-7048.
[28]闫春泽，史玉升，杨劲松，等.晶态与非晶态聚合物在激光烧结中的差异［J］.华中科技大学学报(自然科学版)，2008(3):20-23.(Yan Chun-ze，Shi Yu-sheng，Yang Jin-song，et al.The differences of the selective laser sintering between crystalline and amorphous polymer［J］.Journal of Huazhong University of Science and Technology(Natural Science Edition)，2008(3):20-23.)
[29]Bawane K，Erb D，Lu K.Carbon content and pyrolysis atmosphere effects on phase development in SiOC systems［J］.Journal of the European Ceramic Society，2019，39(9):2846-2854.
[30]潘建梅，严学华，程晓农，等.前驱体热解制备多孔SiOC复合材料及性能［J］.硅酸盐学报，2016，44(12):1740-1747.(Pan Jian-mei，Yan Xue-hua，Cheng Xiao-nong，et al.Preparation of porsor SiOC composite via pyrolysis of polymer precursor and its properties［J］.Journal of Chinese Ceramic Society，2016，44(12):1740-1747.)

纳米SiC粉末对先驱体陶瓷增材性能的影响

Effect of Nano-Sized SiC Powder Filler on Additive Manufactured Properties of Precursor-Derived Ceramics

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 0

编辑推荐

Metrics

本文评价