东北大学学报(自然科学版) ›› 2023, Vol. 44 ›› Issue (7): 1034-1040.DOI: 10.12068/j.issn.1005-3026.2023.07.016

• 资源与土木工程 • 上一篇    下一篇

酸碱交互腐蚀对芳纶滤料性能的影响

柳静献, 代峰, 毛宁   

  1. (东北大学 资源与土木工程学院, 辽宁 沈阳110819)
  • 发布日期:2023-07-13
  • 通讯作者: 柳静献
  • 作者简介:柳静献(1966-),男,河北元氏人,东北大学教授,博士生导师.
  • 基金资助:
    “十三五”国家重点研发计划项目(2017YFC0211801,2016YFC0203701,2016YFC0801605); 国家自然科学基金资助项目(52174215); 辽宁省重点研发计划项目(2019JH2/10100004); 浙江省重点研发计划项目(2020C03089); 辽宁省兴辽人才计划项目(XLYC2002091); 沈阳市社会治理科技专项(20-206-4-09); 辽宁省揭榜挂帅科技攻关专项(2021JH1/10400023).

Effect of Acid-Base Interaction Corrosion on Properties of Aramid Filter

LIU Jing-xian, DAI Feng, MAO Ning   

  1. School of Resources & Civil Engineering, Northeastern University, Shenyang 110819, China.
  • Published:2023-07-13
  • Contact: LIU Jing-xian
  • About author:-
  • Supported by:
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摘要: 工业高温烟气常含有微量SOx而呈弱酸性,在脱硝处理时氨逃逸会使其呈现波动性的微碱性,对袋式除尘滤料形成酸碱交互腐蚀,导致滤袋失效.为探究酸碱交互腐蚀作用对滤料过滤性能的影响,对不同实验处理方法的芳纶滤料的机械性能、表面形貌、化学组成、过滤性能的测试结果进行了研究.结果表明:经20%的 NaOH溶液和35%的 H2SO4溶液二次交互腐蚀,经、纬向强力保持率分别为53.76%,41.26%;断裂伸长保持率分别为40.23%,63.69%;厚度升高了6.55%,面密度降低了5.18%;处理后纤维表面变得粗糙、有纵向凹槽和横向裂纹;酸碱交互腐蚀对芳纶滤料性能造成破坏的本质原因是滤料中的酰胺基团被破坏,使大分子链断裂,且破坏程度随溶液中酸碱的质量分数及酸碱腐蚀顺序的改变而变化.

关键词: 滤料;酸碱交互腐蚀;力学性能;红外光谱;过滤性能

Abstract: Industrial high-temperature flue gas often contains trace amounts of SOx and is weakly acidic. During denitrification treatment, ammonia escape will make it slightly alkaline with fluctuation, which will cause acid-base interactive corrosion of bag-type dust filter material, resulting in the failure of filter bag. In order to explore the effect of acid-base interaction corrosion on the filtration performance of the filter material, the mechanical properties, surface morphology, chemical composition and filtration performance of the aramid filter with different experimental treatment methods were studied. The results show that 20% NaOH solution and 35% H2SO4 solution are secondary interactively corroded. The strength retention rates of warp and zonal are 53.76%, 41.26%, respectively. The elongation retention rate at break are 40.23%, 63.69%, respectively. The thickness is increased by 6.55% and the surface density is decreased by 5.18%. After treatment, the fiber surface becomes rough, with longitudinal grooves and transverse cracks. The essential reason for the damage caused by acid-base interaction corrosion on the performance of aramid filter is that the amide group in the filter is destroyed, so that the macromolecular chain is broken, and the degree of damage varies with the mass fraction of acid and alkali in the solution and the change in the order of acid-base corrosion.

Key words: filter; acid-base interaction corrosion; mechanical behavior; infrared spectrum; filtration performance

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