基于缺陷工程调控多壁碳纳米管的微波吸收性能

doi:10.12068/j.issn.1005-3026.2025.20240203

东北大学学报（自然科学版） ›› 2025, Vol. 46 ›› Issue (8): 133-139.DOI: 10.12068/j.issn.1005-3026.2025.20240203

• 研究论文 • 上一篇

基于缺陷工程调控多壁碳纳米管的微波吸收性能

李逸兴¹, 张璞¹, 孙卓¹, 张雪峰¹^,²

^1.东北大学材料科学与工程学院，辽宁沈阳 110819
^2.杭州电子科技大学材料与环境工程学院，浙江杭州 310012

收稿日期:2024-11-04 出版日期:2025-08-15 发布日期:2025-11-24
通讯作者: 李逸兴
作者简介:李逸兴（1992—），男，陕西宝鸡人，东北大学副教授，博士生导师.
基金资助:
国家自然科学基金资助项目(52225312);国家自然科学基金资助项目(52201202);国家自然科学基金资助项目(52477021);辽宁省自然科学基金资助项目(2024-MSBA-31)

Regulating Microwave Absorption Performance of Multi-walled Carbon Nanotubes Based on Defect Engineering

Yi-xing LI¹, Pu ZHANG¹, Zhuo SUN¹, Xue-feng ZHANG¹^,²

^1.School of Materials Science & Engineering，Northeastern University，Shenyang 110819，China
^2.College of Materials and Environmental Engineering，Hangzhou Dianzi University，Hangzhou 310012，China.

Received:2024-11-04 Online:2025-08-15 Published:2025-11-24
Contact: Yi-xing LI

摘要/Abstract

摘要：

为了提升多壁碳纳米管（MWCNTs）的微波吸收性能，采用缺陷工程策略，通过改变硝酸浓度在MWCNTs中引入结构缺陷调控缺陷密度.结果表明，经7.32 mol/L硝酸处理的样品在13.3 GHz处的最小反射损耗达-43.8 dB，有效吸收带宽为3.3 GHz，显著优于原始样品和过度蚀刻样品，适度的缺陷密度可提升微波吸收性能，过度蚀刻会破坏石墨结构导致性能下降.这种通过单一材料缺陷调控而非传统复合材料设计的方法，不仅简化了工艺，还为微波吸收材料的性能优化提供了新思路.

关键词: 微波吸收材料, 多壁碳纳米管, 缺陷工程, 缺陷密度, 微波吸收

Abstract:

To improve the microwave absorption performance of multi-walled carbon nanotubes （MWCNTs）， a defect engineering strategy was employed by introducing structural defects to modulate defect density through nitric acid treatment with varying concentrations. The results demonstrate that sample treated with 7.32 mol/L nitric acid achieves a minimum reflection loss of -43.8 dB at 13.3 GHz and an effective absorption bandwidth of 3.3 GHz， significantly outperforming both pristine and over-etched samples. Moderate defect density enhances microwave absorption performance， while excessive etching degrades the graphitic structure and deteriorates performance. This approach， based on defect modulation in a single material rather than traditional composite material design， not only simplifies the fabrication process but also provides new insights for optimizing the performance of microwave absorbing materials.

Key words: microwave absorbing material, multi-walled carbon nanotube, defect engineering, defect density, microwave absorption

中图分类号:

TB 34

李逸兴, 张璞, 孙卓, 张雪峰. 基于缺陷工程调控多壁碳纳米管的微波吸收性能[J]. 东北大学学报（自然科学版）, 2025, 46(8): 133-139.

Yi-xing LI, Pu ZHANG, Zhuo SUN, Xue-feng ZHANG. Regulating Microwave Absorption Performance of Multi-walled Carbon Nanotubes Based on Defect Engineering[J]. Journal of Northeastern University(Natural Science), 2025, 46(8): 133-139.

图/表 6

图1 样品的物相分析及拉曼光谱分析（a）—缺陷多壁碳纳米管制备示意图；（b）—样品的XRD谱；（c）—样品的XRD局部放大图；（d）—样品的拉曼光谱；（e）—ID/IG与I2D/IG；（f）—样品的微观结构特征.

Fig.1 Characterization of phase composition and Raman spectrum analysis of the samples

图2 样品的TEM照片

Fig.2 TEM images of the samples

图3 样品的散射参数（a）—反射系数；（b）—透射系数；（c）—吸收系数.

Fig.3 Scattering parameters of the samples

图4 样品的复介电常数和复磁导率（a）—ε'；（b）—ε"；（c）—复磁导率实部；（d）—复磁导率虚部.

Fig.4 Complex dielectric constant and complex permeability of the samplesε'f=12πfτε"f+ε∞. （6）

图5 ε'与B0关系（a）—N0；（b）—N1；（c）—N2.

Fig.5 Relationship between ε' and B0

图6 样品的微波吸收性能（a）~（c）—反射损耗三维图；（d）~（f）—反射损耗二维图；（g）~（i）—不同厚度的带宽和最小反射损耗.

Fig.6 Microwave absorption performance of samples

参考文献 28

[1]	Elmahaishi M F， Azis R S， Ismail I， et al. A review on electromagnetic microwave absorption properties： their materials and performance［J］. Journal of Materials Research and Technology， 2022， 20： 2188-2220.
[2]	Zhao Y Z， Wang W， Wang J N， et al. Constructing multiple heterogeneous interfaces in the composite of bimetallic MOF-derivatives and rGO for excellent microwave absorption performance［J］. Carbon， 2021， 173： 1059-1072.
[3]	Kim S H， Lee S Y， Zhang Y L， et al. Carbon-based radar absorbing materials toward stealth technologies［J］. Advanced Science， 2023， 10（32）： 2303104.
[4]	张亚坤，曾凡，戴全辉，等.雷达隐身技术智能化发展现状与趋势［J］.战术导弹技术， 2019（1）： 56-63.
	Zhang Ya-kun， Zeng Fan， Dai Quan-hui， et al. Development status and trend of intelligent development of radar stealth technology［J］. Tactical Missile Technology， 2019（1）： 56-63.
[5]	钟国媛，董季玲，石小雪，等. Fe-MOFs衍生碳基吸波材料研究进展［J］.电子元件与材料， 2024， 43（2）： 127-136.
	Zhong Guo-yuan， Dong Ji-ling， Shi Xiao-xue， et al. Research progress of carbon-based wave-absorbing materials derived from Fe-MOFs［J］. Electronic Components and Materials， 2024， 43（2）： 127-136.
[6]	Li Y X， Liao Y J， Ji L Z， et al. Quinary high-entropy-alloy@graphite nanocapsules with tunable interfacial impedance matching for optimizing microwave absorption［J］. Small， 2022， 18（4）： 2107265.
[7]	Shi X F， You W B， Zhao Y H， et al. Multi-scale magnetic coupling of Fe@SiO₂@C-Ni yolk@triple-shell microspheres for broadband microwave absorption［J］. Nanoscale， 2019， 11（37）： 17270-17276.
[8]	刘祥萱，王煊军，崔虎. 雷达波吸收材料设计与特性分析［M］.北京：国防工业出版社， 2018.
	Liu Xiang-xuan， Wang Xuan-jun， Cui Hu. Design and property analysis of radar absorbing materials ［M］. Beijing： National Defense Industry Press， 2018.
[9]	Zhang N， Huang Y， Wang M Y. Synthesis of graphene/thorns-like polyaniline/α-Fe₂O₃@SiO₂ nanocomposites for lightweight and highly efficient electromagnetic wave absorber［J］. Journal of Colloid and Interface Science， 2018， 530： 212-222.
[10]	Tang J M， Liang N， Wang L， et al. Three-dimensional nitrogen-doped reduced graphene oxide aerogel decorated with Ni nanoparticles with tunable and unique microwave absorption［J］. Carbon， 2019， 152： 575-586.
[11]	Zhang X F， Guan P F， Dong X L. Multidielectric polarizations in the core/shell Co/graphite nanoparticles［J］. Applied Physics Letters， 2010， 96（22）： 223111.
[12]	Feng Y， Li D， Bai Y， et al. The effect of core-shell structure on microwave absorption properties of graphite-coated magnetic nanocapsules［J］. Journal of Electronic Materials， 2019， 48（3）： 1429-1435.
[13]	Li X A， Du D X， Wang C S， et al. In situ synthesis of hierarchical rose-like porous Fe@C with enhanced electromagnetic wave absorption［J］. Journal of Materials Chemistry C， 2018， 6（3）： 558-567.
[14]	Zhao H B， Cheng J B， Zhu J Y， et al. Ultralight CoNi/rGO aerogels toward excellent microwave absorption at ultrathin thickness［J］. Journal of Materials Chemistry C， 2019， 7（2）： 441-448.
[15]	Li X Y， Lu K. Playing with defects in metals［J］. Nature Materials， 2017， 16（7）： 700-701.
[16]	Dresselhaus M S， Jorio A， Hofmann M， et al. Perspectives on carbon nanotubes and graphene Raman spectroscopy［J］. Nano Letters， 2010， 10（3）： 751-758.
[17]	Xu X， Guo Y， Bloom B P， et al. Elemental core level shift in high entropy alloy nanoparticles via X-ray photoelectron spectroscopy analysis and first-principles calculation［J］. ACS Nano， 2020， 14（12）： 17704-17712.
[18]	Ferrari A C， Basko D M. Raman spectroscopy as a versatile tool for studying the properties of graphene［J］. Nature Nanotechnology， 2013， 8（4）： 235-246.
[19]	Cançado L G， Jorio A， Martins F E H， et al. Quantifying defects in graphene via Raman spectroscopy at different excitation energies［J］. Nano Letters， 2011， 11（8）： 3190-3196.
[20]	Cançado L G， Takai K， Enoki T， et al. General equation for the determination of the crystallite size L_a of nanographite by Raman spectroscopy［J］. Applied Physics Letters， 2006， 88（16）： 163106.
[21]	Zafar Z， Ni Z H， Wu X， et al. Evolution of Raman spectra in nitrogen doped graphene［J］. Carbon， 2013， 61： 57-62.
[22]	Eigler S， Dotzer C， Hirsch A. Visualization of defect densities in reduced graphene oxide［J］. Carbon， 2012， 50（10）： 3666-3673.
[23]	宋玉娟. 多壁碳纳米管的缺陷调控及微波吸收性能研究［D］.沈阳：东北大学， 2021.
	Song Yu-juan. Study on defect control and microwave absorption properties of multi-walled carbon nanotubes［D］. Shenyang： Northeastern University， 2021.
[24]	Brosseau C， NDong W， Mdarhri A. Influence of uniaxial tension on the microwave absorption properties of filled polymers［J］. Journal of Applied Physics， 2008， 104（7）： 074907.
[25]	Qin F X， Brosseau C， Peng H X， et al. In situ microwave characterization of microwire composites with external magnetic field［J］. Applied Physics Letters， 2012， 100（19）： 192903.
[26]	Li Y X， Liu R G， Pang X Y， et al. Fe@C nanocapsules with substitutional sulfur heteroatoms in graphitic shells for improving microwave absorption at gigahertz frequencies［J］. Carbon， 2018， 126： 372-381.
[27]	Li Y X， Wang J Y， Liu R G， et al. Dependence of gigahertz microwave absorption on the mass fraction of Co@C nanocapsules in composite［J］. Journal of Alloys and Compounds， 2017， 724： 1023-1029.
[28]	Wang J Y， Wang Z H， Liu R G， et al. Heterogeneous interfacial polarization in Fe@ZnO nanocomposites induces high-frequency microwave absorption［J］. Materials Letters， 2017， 209： 276-279.

基于缺陷工程调控多壁碳纳米管的微波吸收性能

Regulating Microwave Absorption Performance of Multi-walled Carbon Nanotubes Based on Defect Engineering

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