东北大学学报(自然科学版) ›› 2008, Vol. 29 ›› Issue (2): 246-249.DOI: -

• 论著 • 上一篇    下一篇

铝电解用SiC-Si_3N_4绝缘侧壁材料耐腐蚀性能测试方法

曹晓舟;高炳亮;王兆文;张廷安;   

  1. 东北大学材料与冶金学院;东北大学材料与冶金学院;东北大学材料与冶金学院;东北大学材料与冶金学院 辽宁沈阳110004;辽宁沈阳110004;辽宁沈阳110004;辽宁沈阳110004
  • 收稿日期:2013-06-22 修回日期:2013-06-22 出版日期:2008-02-15 发布日期:2013-06-22
  • 通讯作者: Cao, X.-Z.
  • 作者简介:-
  • 基金资助:
    国家自然科学基金资助项目(50674031)

Anti-corrosion testing of SiC-Si3N4 insulation sidelining for aluminum electrolysis

Cao, Xiao-Zhou (1); Gao, Bing-Liang (1); Wang, Zhao-Wen (1); Zhang, Ting-An (1)   

  1. (1) School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China
  • Received:2013-06-22 Revised:2013-06-22 Online:2008-02-15 Published:2013-06-22
  • Contact: Cao, X.-Z.
  • About author:-
  • Supported by:
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摘要: 研究了氮化硅结合碳化硅材料耐腐蚀性能的测试方法.这种方法是在冰晶石-氧化铝熔盐体系中通入二氧化碳气体来模拟实际电解过程中电解槽内部的工作状态.试样置于盛有高温熔盐的石墨坩埚中,二氧化碳气体的通入造成试样的动态腐蚀,测定电解质和二氧化碳气体共侵蚀作用下的试样体积变化率.与静态电解质腐蚀方法所得实验数据比较,试样腐蚀程度高很多,说明二氧化碳气体对试样的耐腐蚀性能影响很大.应用该方法对三个不同厂家所生产的氮化硅结合碳化硅材料进行动态腐蚀测试,并采用该方法制定的测试标准对试样的耐腐蚀性能进行评价.结果表明,该测试方法简单,易操作,且能够真实模拟电解槽内衬材料在铝电解槽中的腐蚀状态,并且对于试样的性能有...

关键词: 氮化硅结合碳化硅, 耐腐蚀性能, 铝电解槽, 槽侧壁, 测试方法

Abstract: A new method was applied to the test of corrosion resistance of SiC-Si3N4 material. It refers to that the cryolite-alumina melt is aerated so as to simulate a working state inside the cell during Al electrolysis, then a specimen is put into a graphite crucible where the high-temperature molten salt was contained before. The CO2 aeration makes the specimen dynamically corrosive. Then, the volume change rate of the specimen under the joint action of electrolyte and CO2 gas is tested and compared with the data resulting from static electrolyte corrosion test. The specimen presents much higher corrosion. It means that CO2 gas has greater effect on corrosion resistance. The new dynamic corrosion method was applied to the SiC-Si3N4 samples supplied by three different firms and, according to the testing standard based on the method, the results were evaluated for their anti-corrosion properties. The method is simple and efficient to simulate the corrosion behavior of the inner lining materials in aluminum electrolysis cell and evaluate their anti-corrosion properties.

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