Abstract: This paper studies the relationship between the structure of export commodities and Environment pollution.We find the optimization of the export commodities will worse Environment pollution by building mathematical model. And we do a empirical test using the data of industrial waste gas from 1981 to 2010.It shows that the optimization of the export commodities has a positive effect to the industrial waste gas. At last the conclusion of this paper shows that it is impossible to improve the level of our Environment pollution by only using the way of the optimization of the export commodities

Key words: structure of export commodities；environment pollution；industrial waste gas