东北大学学报（自然科学版）

东北大学学报:自然科学版 ›› 2015, Vol. 36 ›› Issue (11): 1596-1600.DOI: 10.12068/j.issn.1005-3026.2015.11.017

• 材料与冶金 • 上一篇    下一篇

硼泥的熔碱浸出脱硅

宁志强， 李晓侠， 翟玉春， 贾超航   

  1. (东北大学 材料与冶金学院， 辽宁 沈阳110819)
  • 收稿日期:2014-12-17 修回日期:2014-12-17 出版日期:2015-11-15 发布日期:2015-11-10
  • 通讯作者: 宁志强
  • 作者简介:宁志强(1978-)，男，辽宁沈阳人，东北大学讲师，博士； 翟玉春(1946-)，男，辽宁鞍山人，东北大学教授，博士生导师.
  • 基金资助:
    国家自然科学基金资助项目(51204037)； 格平绿色助学行动——辽宁环境科研“123”工程.

Desilication of Boron Mud Using Molten Sodium Hydroxide Media

NING Zhi-qiang， LI Xiao-xia， ZHAI Yu-chun， JIA Chao-hang   

  1. School of Materials & Metallurgy， Northeastern University， Shenyang 110819， China.
  • Received:2014-12-17 Revised:2014-12-17 Online:2015-11-15 Published:2015-11-10
  • Contact: NING Zhi-qiang
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摘要： 为实现硼泥的综合利用，采用熔碱介质对硼泥进行脱硅处理，考察了反应时间、反应温度及碱矿质量比对硼泥中二氧化硅提取率的影响.在此基础上，通过正交实验，确定最佳的脱硅反应条件.研究结果表明，最佳的脱硅反应条件: 反应时间20min，反应温度550℃，碱矿质量比为1.75∶1.此时，硅的提取率可达91.9%，硼泥脱硅渣中氧化镁的质量分数为92.04%，利用X射线衍射分析仪(XRD)和扫描电镜(SEM)对硼泥脱硅渣进行了表征.

关键词: 硼泥, 氢氧化钠, 脱硅, 氧化镁, 正交实验

Abstract: To accomplish the comprehensive utilization of boron mud， the desilication of boron mud was studied using molten sodium hydroxide media. The effect on silicon dioxide extraction ratio caused by the factors， such as reaction time， reaction temperature and mass ratio of sodium hydroxide to boron mud， was analyzed. The optimum reaction condition of desilication was obtained through the orthogonal tests. The results showed that the extraction ratio of silicon dioxide reaches 91.9% and MgO content reaches 92.04% in the solid residuals under the optimum reaction conditions of desilication. The reaction time is 20min， the reaction temperature is 550℃ and the mass ratio of sodium hydroxide to boron mud is 1.75∶1. The solid residuals were characterized by XRD and SEM.

Key words: boron mud, sodium hydroxide, desilicication, magnesium oxide, orthogonal test

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