东北大学学报（自然科学版）

东北大学学报:自然科学版 ›› 2016, Vol. 37 ›› Issue (8): 1113-1117.DOI: 10.12068/j.issn.1005-3026.2016.08.011

• 材料与冶金 • 上一篇    下一篇

乙二胺合钴-尿素络合法脱除NO的实验研究

秦勤1， 王宁1， 孙明雪1， 刘杰2   

  1. (1. 东北大学 冶金学院， 辽宁 沈阳110819； 2. 洛伊热工工程有限公司， 天津300192)
  • 收稿日期:2015-05-15 修回日期:2015-05-15 出版日期:2016-08-15 发布日期:2016-08-12
  • 通讯作者: 秦勤
  • 作者简介:秦勤(1965-)，女，山东阳谷人，东北大学副教授.
  • 基金资助:
    国家自然科学基金资助项目(51274066).

Experimental Study on Removal of NO by Using Co(en)3+3 and Urea Complexation

QIN Qin1， WANG Ning1， SUN Ming-xue1， LIU Jie2   

  1. 1.School of Metallurgy， Northeastern University， Shenyang 110819， China; 2. LOI Thermprocess Co.， Ltd.， Tianjin 300192， China.
  • Received:2015-05-15 Revised:2015-05-15 Online:2016-08-15 Published:2016-08-12
  • Contact: QIN Qin
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摘要： 在半连续的鼓泡反应器中，对乙二胺合钴-尿素络合法脱除烟气中的NO进行实验研究.结果表明，向尿素溶液中添加乙二胺合钴可以增大溶液中NO2的氧化度和NO的溶解度，使吸收液的脱硝率有较大的提高；增大氧气浓度、Co(en)3+3浓度、NO进口浓度，脱硝率也随之增加；增大尿素浓度，脱硝率增加的幅度较小；增大烟气流量不利于NO的吸收；当pH值为10.4，温度在60~70℃之间时，吸收液可以保持较高的脱硝率.

关键词: 烟气脱硝, 湿法, 乙二胺合钴, 尿素, 脱硝率

Abstract: Experiments on flue gas denitrification by using Co(en)3+3 and urea complexation were performed in a semi-batch bubbling reactor. The results show that the oxidation degree of NO2， the solubility of NO， and the removal rate of NO are increased by adding Co(en)3+3 in the urea solution. The removal rate of NO increases with increasing oxygen concentration， Co(en)3+3concentration and NO inlet concentration， while the removal rate of NO increases slightly with the increase of urea concentration. Increasing gas flow is not conducive to the absorption of NO. The absorption liquid maintains the high removal rate of NO when the pH value is 10.4 and the temperature is between 60 and 70℃.

Key words: flue gas denitrification, wet process, Co(en)3+3, urea, removal rate of NO

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