东北大学学报（自然科学版）

东北大学学报(自然科学版) ›› 2013, Vol. 34 ›› Issue (10): 1400-1403.DOI: -

• 材料与冶金 • 上一篇    下一篇

微量Ga对电容器阳极用铝箔组织及比电容的影响

左宏1，李新芳2，刘春明1   

  1. (1.东北大学材料各向异性与织构教育部重点实验室，辽宁沈阳110819；2.新疆众和股份有限公司，新疆乌鲁木齐830013)
  • 收稿日期:2013-02-23 修回日期:2013-02-23 出版日期:2013-10-15 发布日期:2013-05-24
  • 通讯作者: 左宏
  • 作者简介:左宏(1982-)，男，新疆乌鲁木齐人，东北大学博士研究生，新疆众和股份有限公司工程师；刘春明(1961-)，男，陕西渭南人，东北大学教授，博士生导师.
  • 基金资助:
    长江学者和创新团队发展计划项目(IRT0713).

Effects of Trace Ga on Microstructure and Specific Capacitance of Aluminum Foils Used for Capacitor Anodes

ZUO Hong1， LI Xinfang2， LIU Chunming1   

  1. 1. Key Laboratory for Anisotropy and Texture of Materials， Ministry of Education， Northeastern University， Shenyang 110819， China; 2. Xinjiang Zhonghe JointStock Co. Ltd.， Wulumuqi 830013， China.
  • Received:2013-02-23 Revised:2013-02-23 Online:2013-10-15 Published:2013-05-24
  • Contact: LIU Chunming
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摘要： 采用X射线衍射定量检测含微量Ga高压电解电容器阳极用退火箔的立方织构，用金相显微镜及扫描电镜观察其显微组织，用图像分析软件分析腐蚀箔的腐蚀结构，研究了微量Ga对组织结构、腐蚀结构及比电容的影响.结果表明:Ga的质量分数由05×10-6提高至116×10-6时，铝箔的立方织构的体积分数略微下降，但在520V的比电容却由0662μF/cm2增加到0706μF/cm2；当Ga的质量分数增加至214×10-6时，显微组织及织构变化不明显，但比电容下降至0693μF/cm2.这是因为适当添加微量Ga能促进电化学腐蚀发孔，增加箔的表面积，提高其比电容；但Ga的质量分数高于116×10-6时，将增加箔的并孔数量，减少其表面积，导致比电容下降.

关键词: 电解电容器, 高压铝箔, 微量镓, 比电容, 立方织构

Abstract: The cubic texture of the annealed high purity aluminum foils with trace Ga used for the anode of high voltage electrolytic capacitors was quantitatively characterized by Xray diffractometer (XRD). The microstructures of their hotrolled plates and final annealed foils were observed by optical microscope(OM) and scanning electron microscope (SEM). The corrosion structures of the etched foils were quantitatively analyzed with image analysis software. Based on the above experiments the effects of the mass fraction of trace Ga on the microstructures and the corrosion structure as well as the specific capacitance were investigated. The results showed that with the mass fraction of Ga increasing from 05×10-6 to 116×10-6， the volume fraction of cubic texture in the foils decreased slightly， but the specific capacitance of the foils measured at 520V increased from 0662μF/cm2 to 0706μF/cm2. Further increasing the mass fraction of Ga to 214×10-6 did not affect the microstructure and the fraction of the cubic texture， but the specific capacitance dropped to 0693μF/cm2. Adding trace Ga promoted the electrochemical pitting and resulted in the enlargement of the specific surface area of the foil and the improvement of the specific capacitance. However when the mass fraction of Ga was higher than 116×10-6， obvious pit merging occurred， the specific surface area of the foil reduced and the specific capacitance decreased.

Key words: electrolytic capacitor, high voltage aluminum foil, trace Ga, specific capacitance, cubic texture

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