NiMnGaTi铁磁形状记忆合金的马氏体相变和磁性能

doi:10.12068/j.issn.1005-3026.2019.10.006

东北大学学报:自然科学版 ›› 2019, Vol. 40 ›› Issue (10): 1398-1402.DOI: 10.12068/j.issn.1005-3026.2019.10.006

NiMnGaTi铁磁形状记忆合金的马氏体相变和磁性能

白静^1,2，杨禛²，赵晨羽²，赵骧¹

(1. 东北大学材料各向异性与织构教育部重点实验室，辽宁沈阳110819; 2. 东北大学秦皇岛分校资源与材料学院，河北秦皇岛066004)

收稿日期:2019-01-08 修回日期:2019-01-08 出版日期:2019-10-15 发布日期:2019-10-10
通讯作者: 白静
作者简介:白静(1983-)，女，辽宁开原人，东北大学秦皇岛分校副教授；赵骧(1956-)，男，辽宁沈阳人，东北大学教授，博士生导师.
基金资助:
国家自然科学基金资助项目(51771044，51431005)；国家高技术研究发展计划项目(SS2015AA031803).

Martensitic Transformation and Magnetic Properties of NiMnGaTi Ferromagnetic Shape Memory Alloy

BAI Jing^1,2， YANG Zhen²， ZHAO Chen-yu²， ZHAO Xiang¹

1. Key Laboratory for Anisotropy and Texture of Materials， Northeastern University， Shenyang 110819， China; 2. School of Resources and Materials， Northeastern University at Qinhuangdao， Qinhuangdao 066004， China.

Received:2019-01-08 Revised:2019-01-08 Online:2019-10-15 Published:2019-10-10
Contact: BAI Jing
About author:-
Supported by:
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摘要/Abstract

摘要： 对Ni₅₃Mn_23.5Ga_23.5-○xTi_○x(x=0，2，5和8)系列合金的微观组织、马氏体相变及磁性能进行了研究，探究不同制备方法和不同Ti含量对合金性能的影响规律.研究结果表明:随着Ti含量的增加，合金的晶粒变细且析出物数量显著增加，适量的韧性第二相析出有助于改善合金的高脆性，合金的马氏体相变温度和饱和磁化强度均降低.EDS能谱分析表明，Ti掺杂合金的析出物是富Ni和Ti的第二相.对于Ti₀和Ti₂合金，900r/min甩带样品的饱和磁化强度与铸态样品基本相同，但Ti₅和 Ti₈甩带样品的磁化强度明显高于铸态，这是甩带工艺抑制非磁性的第二相析出所致.

关键词: 铁磁形状记忆合金, NiMnGaTi, 快速甩带, 马氏体相变, 饱和磁化强度

Abstract: The microstructure， martensitic transformation and magnetic properties of Ni₅₃Mn_23.5Ga_23.5-○xTi_○x○(x=0， 2， 5 and 8)ferromagnetic shape memory alloys were studied to investigate the effects of different preparation methods and different Ti contents on the martensitic transformation and magnetic properties. The results show that when the Ti content increases， the grain size becomes finer， the martensitic transformation temperatures and martensitic transformation decrease， and the precipitate density increases where the appropriate amount of second-phase precipitations can facilitate to improve the high brittleness of the alloy. The EDS analysis indicates that in Ti doping alloys， the second-phase precipitation is rich in Ni and Ti constituents. The Ti addition decreases the saturation magnetization dramatically. The saturation magnetizations of Ti₀ and Ti₂ melt spun ribbons at the rotation speed of 900r/min are almost the same as those of the as-cast samples. However， the saturation magnetizations of the Ti₅ and Ti₈ melt spun samples are obviously higher than those of the as-cast ones， because the non-magnetic second-phase precipitations are suppressed in the melt spun process.

Key words: ferromagnetic shape memory alloy, NiMnGaTi, melt spun ribbon, martensitic transformation, saturation magnetization

中图分类号:

TG139.6

白静，杨禛，赵晨羽，赵骧. NiMnGaTi铁磁形状记忆合金的马氏体相变和磁性能[J]. 东北大学学报:自然科学版, 2019, 40(10): 1398-1402.

BAI Jing， YANG Zhen， ZHAO Chen-yu， ZHAO Xiang. Martensitic Transformation and Magnetic Properties of NiMnGaTi Ferromagnetic Shape Memory Alloy[J]. Journal of Northeastern University Natural Science, 2019, 40(10): 1398-1402.

参考文献

[1]Ullakko K，Huang J K，Kantner C，et al.Large magnetic-field-induced strains in Ni₂MnGa single crystals［J］.Applied Physics Letters，1996，69:1966-1968.
[2]Ullakko K，Huang J K，Kokorin V V，et al.Magnetically controlled shape memory effect in Ni₂MnGa intermetallics［J］.Scripte Material，1997，36(10):1133-1138.
[3]Murray S J，Marioni M，Allen S M，et al.6% magnetic-field-induced strain by twin-boundary motion in ferromagnetic Ni-Mn-Ga［J］. Applied Physics Letters，2000，77:886-888.
[4]Xin Y，Zhou Y.Martensitic transformation and mechanical properties of NiMnGaV high-temperature shape memory alloys［J］.Intermetallics，2016，73:50-57.
[5]Wang H B，Chen F，Gao Z Y，et al.Effect of Fe content on fracture behavior of Ni-Mn-Fe-Ga ferromagnetic shape memory alloys［J］.Materials Science & Engineering A，2006，438/439/440(1):990-993.
[6]Tsuchiya K，Tsutsumi A，Ohtsuka H，et al.Modification of Ni-Mn-Ga ferromagnetic shape memory alloy by addition of rare earth elements［J］.Materials Science & Engineering A，2004，378(1/2):370-376.
[7]Li Y Y，Wang J M，Jiang C B.Study of Ni-Mn-Ga-Cu as single-phase wide-hysteresis shape memory alloys［J］.Materials Science & Engineering A，2011，528(22/23):6907-6911.
[8]白静，李泽，万震，等.NiMnGaCu铁磁形状记忆合金的晶体结构、相稳定性和磁性能的第一性原理研究［J］.金属学报，2017，53(1):83-89.(Bai Jing，Li Ze，Wan Zhen，et al.First-principles study on crystal structure，phase stability and magnetic properties of Ni-Mn-Ga-Cu ferromagnetic shape memory alloy ［J］.Acta Metallurgica Sinica，2017，53(1):83-89.)
[9]Dong G F，Cai W，Gao Z Y.Microstructure and martensitic transformation of NiMnGaTi ferromagnetic shape memory alloys［J］.Journal of Alloys and Compounds，2008，465(1):173-176.
[10]Dong G F，Gao Z Y，Zhang X L，et al.Phase transition and mechanical properties of constraint-aged NiMnGaTi magnetic shape memory alloy［J］.Journal of Materials Science，2011，46(13):4562-4567.
[11]Gao Z Y，Dong G F，Cai W，et al.Martensitic transformation and mechanical properties in an aged NiMnGaTi ferromagnetic shape memory alloy［J］.Journal of Alloys and Compounds，2009，481(1/2):44-47.
[12]Dong G F，Cai W，Gao Z Y，et al.Effect of isothermal ageing on microstructure，martensitic transformation and mechanical properties of Ni₅₃Mn_23.5Ga_18.5Ti₅ ferromagnetic shape memory alloy［J］.Scripta Materialia，2008，58(8):647-650.
[13]Dong G F，Cai W，Gao Z Y.Microstructure and martensitic transformation of NiMnGaTi ferromagnetic shape memory alloys［J］. Journal of Alloys and Compounds，2008，465(1):173-176.

NiMnGaTi铁磁形状记忆合金的马氏体相变和磁性能

Martensitic Transformation and Magnetic Properties of NiMnGaTi Ferromagnetic Shape Memory Alloy

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