东北大学学报（自然科学版）

东北大学学报(自然科学版) ›› 2004, Vol. 25 ›› Issue (11): 1072-1075.DOI: -

• 论著 • 上一篇    下一篇

Fe-Nb-B纳米晶合金的结构与磁性

支起铮;王继杰;陈文智;何开元   

  1. 东北大学材料与冶金学院;东北大学材料与冶金学院;钢铁研究总院国家非晶微晶合金工程技术研究中心;东北大学材料与冶金学院 辽宁沈阳　110004
  • 收稿日期:2013-06-24 修回日期:2013-06-24 出版日期:2004-11-15 发布日期:2013-06-24
  • 通讯作者: Zhi, Q.-Z.
  • 作者简介:-
  • 基金资助:
    国家自然科学基金资助项目(50244022)

Structure and magnetic properties of nanocrystalline Fe-Nb-B alloys

Zhi, Qi-Zheng (1); Wang, Ji-Jie (1); Chen, Wen-Zhi (2); He, Kai-Yuan (1)   

  1. (1) Sch. of Mat. and Metall., Northeastern Univ., Shenyang 110004, China; (2) Natl. Amorphous Alloy Eng. Ctr., Beijing Central Iron and Steel Inst., Beijing 100081, China
  • Received:2013-06-24 Revised:2013-06-24 Online:2004-11-15 Published:2013-06-24
  • Contact: Zhi, Q.-Z.
  • About author:-
  • Supported by:
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摘要： 利用X射线衍射,差热分析及静态磁性测量,研究了退火温度对不同成分的非晶Fe Nb B合金纳米晶化行为和磁性的影响·实验发现:在纳米晶化过程的初期出现磁硬化,矫顽力与最大磁导率均呈现不同程度的恶化·在硼化物(Fe2B和Fe3B)相析出前,具有纳米结构的合金由α Fe固溶体和非晶基体相组成,呈现较佳的软磁特性·随纳米晶相体积分数增加而呈现的磁软化现象可解释为由于纳米晶粒间距的减少,交换耦合增强所致·

关键词: 纳米晶合金, 非晶合金, 磁性, 晶化, FeNbB合金

Abstract: The effects of annealing temperature on nanocrystallization behavior and magnetic properties of amorphous Fe-Nb-B alloys were investigated by X-ray diffraction, differential scanning calorimeter and static magnetism measurement. It is found in experiment that the magnetic hardening takes place somewhat at the beginning of nanocrystallization process, which is manifested differently by the deterioration of coercive force and maximum permeability. The softer magnetic behavior features the alloys, of which the nanocrystallization structure is composed of α-Fe solid solution and amorphous matrix just before the precipitation of borides (e. g. Fe2B and Fe3B). The magnetic softening was observed increasing with the increase of the volume fraction of nanocrystallization phase, which can be explained by the reason that the decrease in the distance between nanocrystals will result in stronger exchange coupling.

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