东北大学学报:自然科学版 ›› 2015, Vol. 36 ›› Issue (9): 1273-1277.DOI: 10.3969/j.issn.1005-3026.2015.09.013

• 材料与冶金 • 上一篇    下一篇

硫质量分数对Ti-Zr脱氧E36钢中夹杂物的影响

战东平1, 唐磊1, 姜周华1, 张慧书2   

  1. (1. 东北大学 材料与冶金学院, 辽宁 沈阳110819; 2. 辽宁科技学院 冶金学院, 辽宁 本溪117004)
  • 收稿日期:2014-08-06 修回日期:2014-08-06 出版日期:2015-09-15 发布日期:2015-09-14
  • 通讯作者: 战东平
  • 作者简介:战东平(1976-),男,黑龙江鹤岗人,东北大学副教授; 姜周华(1963-),男,浙江萧山人,东北大学教授,博士生导师.
  • 基金资助:
    国家高技术研究发展计划项目(2012AA03A503); 辽宁科技学院博士启动基金资助项目(1406B06).

Effect of Sulfur Mass Fraction on Inclusions in Steel E36 Deoxidized by Titanium and Zirconium

ZHAN Dong-ping1, TANG Lei1, JIANG Zhou-hua1, ZHANG Hui-shu2   

  1. 1. School of Materials & Metallurgy, Northeastern University, Shenyang 110819, China; 2. School of Metallurgy, Liaoning Institute of Science and Technology, Benxi 117004, China.
  • Received:2014-08-06 Revised:2014-08-06 Online:2015-09-15 Published:2015-09-14
  • Contact: ZHAN Dong-ping
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摘要: 为明确钢中硫质量分数对Ti-Zr脱氧的E36船板钢中夹杂物的影响,在1873K下,在MoSi2电阻炉上用70mm×100mm MgO坩埚开展了3炉E36钢炼钢实验.结果表明,Ti-Zr脱氧钢中夹杂物主要以含TiOx和ZrO2成分的外围包裹MnS的球形夹杂物为主,典型夹杂物为Al2O3-TiOx-MnS,MgO-SiO2-Al2O3,Al2O3-SiO2-TiOx-ZrO2,TiOx-SiO2-Al2O3-MnS等.随着硫质量分数的增加,小于10μm的夹杂物所占比例逐渐提高到99.5%,夹杂物平均直径由1.7μm增大到2.3μm,夹杂物中平均硫质量分数和单个夹杂物中MnS所占的面积百分比均增加,w[S]=0.001 5%时面积比为0.15%,w[S]=0.011%时面积比达到0.72%.

关键词: 炼钢, 船板钢, 硫质量分数, 夹杂物, 脱氧

Abstract: In order to study the effect of sulfur mass fraction on inclusions in steel E36 deoxidized by titanium and zirconium, steelmaking experiments of three heats of steel E36 were done in a MoSi2 furnace with 70mm×100mm MgO crucible at 1873K. The results showed that most of the inclusions in steel E36 deoxidized by titanium and zirconium are spherical inclusions of TiOx and ZrO2 coated by MnS. The typical inclusions are Al2O3-TiOx-MnS, MgO-SiO2-Al2O3, Al2O3-SiO2-TiOx-ZrO2 and TiOx-SiO2-Al2O3-MnS. With the increasing of the sulfur mass fraction in steel, the inclusion percentages with the diameter less than 10μm increase to 99.5%; the average diameter of the inclusions reaches 2.3μm from 1.7μm; the sulfur mass fraction in the inclusions and the area of MnS in single inclusion are also bigger, the area is 0.15% when w[S] is 0.001 5%, and it becomes 0.72% when w [S] is 0.011%.

Key words: steelmaking, ship plate steel, sulfur mass fraction, inclusion, deoxidation

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