东北大学学报（自然科学版）

东北大学学报(自然科学版) ›› 2005, Vol. 26 ›› Issue (3): 278-281.DOI: -

• 论著 • 上一篇    下一篇

钙钛矿对无水硫铝酸钙形成的影响

张巨松;隋智通;回志峰;安会勇   

  1. 东北大学材料与冶金学院;东北大学材料与冶金学院;沈阳建筑大学材料学院;沈阳建筑大学材料学院 辽宁沈阳　110004
  • 收稿日期:2013-06-24 修回日期:2013-06-24 出版日期:2005-03-15 发布日期:2013-06-24
  • 通讯作者: Zhang, J.-S.
  • 作者简介:-
  • 基金资助:
    国家自然科学基金重点资助项目(NO50234040)·

Influence of compound CaOTiO on formation of anhydrous calcium aluminosulphate

Zhang, Ju-Song (1); Shui, Zhi-Tong (1); Hui, Zhi-Feng (2); An, Hui-Yong (2)   

  1. (1) Sch. of Mat. and Metall., Northeastern Univ., Shenyang 110004, China; (2) Mat. Coll., Shenyang Jianzhu Univ., Shenyang 110168, China
  • Received:2013-06-24 Revised:2013-06-24 Online:2005-03-15 Published:2013-06-24
  • Contact: Zhang, J.-S.
  • About author:-
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摘要： 通过化学分析、差热分析和XRD分析系统地研究了钙钛矿对无水硫铝酸钙形成的影响·研究结果表明:钙钛矿的存在对无水硫铝酸钙的原料二水石膏的二次脱水几乎没有影响,随着CT的掺量增加,碳酸钙分解反应的活化能逐步降低,有利于碳酸盐的分解,无水硫铝酸钙合成的开始温度有所降低,游离石膏量减少,f CaO的量逐渐减少,无水硫铝酸钙合成量增加,随着温度的升高,也有利于石膏的分解·

关键词: 钙钛矿, 无水硫铝酸钙, 活化能, 化学分析, 差热分析, XRD分析

Abstract: By means of chemical analysis, thermogravimetry (DTA. TG) and XRD analysis, the influence of compound CaOTiO or CT on the formation of anhydrous calcium aluminosulphate (C4A3S¯) was investigated systematically. The result showed that the compound CaOTiO has almost no effect on the secondary dehydration of dehydrate gypsum as one of the raw materials of C4A3S¯. With the increasing dosage of CT, the activation energy in the decomposition reaction of calcium carbonate gradually lower in value to facilitate calcium carbonate decomposition. Furthermore, the initial synthesizing temperature of calciume drops with the amounts of free gypsum and f-CaO decreasing gradually and the synthesized amount of C4A3S¯ increases. All these facilitate CT the gypsum decomposition with temperature rising.

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