从硼泥中提取硅、硼的新工艺

doi:10.12068/j.issn.1005-3026.2022.07.007

东北大学学报（自然科学版） ›› 2022, Vol. 43 ›› Issue (7): 959-965.DOI: 10.12068/j.issn.1005-3026.2022.07.007

从硼泥中提取硅、硼的新工艺

宁志强，宋雨陶，赵润宇，韩帅男

(东北大学冶金学院，辽宁沈阳110819))

发布日期:2022-08-02
通讯作者: 宁志强
作者简介:宁志强(1978- )，男，辽宁沈阳人，东北大学副教授.
基金资助:
“十三五”国家重点研发计划项目(2017YFB0305401).

New Technology for Extracting Silicon and Boron from Boron Mud

NING Zhi-qiang， SONG Yu-tao， ZHAO Run-yu， HAN Shuai-nan

School of Metallurgy， Northeastern University， Shenyang 110819， China.

Published:2022-08-02
Contact: NING Zhi-qiang
About author:-
Supported by:
-

摘要/Abstract

摘要： 以硼泥为原料，硼泥与碳酸钠混合后在900℃下焙烧2h，采用碱浸法回收焙烧后硼泥中的SiO₂和B₂O₃.通过TG-DSC曲线分析了焙烧阶段的反应过程.通过单因素试验研究了碱浸阶段:n(NaOH)/n(SiO₂)、反应温度、反应时间、液固质量比等条件对硼泥中的SiO₂和B₂O₃提取率的影响.通过正交试验，确定了影响SiO₂提取率各因素之间的主次关系依次为:n(NaOH)/n(SiO₂)＞液固质量比＞反应时间＞反应温度，影响B₂O₃提取率各因素之间的主次关系为:反应时间＞反应温度＞n(NaOH)/n(SiO₂)＞液固质量比.最佳的回收条件:n(NaOH)/n(SiO₂)为25，反应温度为50℃，反应时间为40min，液固质量比为8，在此条件下SiO₂的提取率为83.11%，B₂O₃的提取率为75.28%.

关键词: 硼泥；二氧化硅；氧化硼；碳酸钠；氢氧化钠

Abstract: Taking boron mud as raw material， the boron mud mixed with sodium carbonate was roasted at 900℃ for 2h， and the SiO₂ and B₂O₃ in the roasted boron mud were recovered by alkaline leaching method. The reaction in the calcination stage was analyzed by TG-DSC curve. The effects of n(NaOH)/n(SiO₂)， reaction temperature， reaction time and liquid-solid mass ratio on the extraction ratios of SiO₂ and B₂O₃ in boron mud were studied by single factor experiment. By orthogonal experiment， the order of factors affecting the extraction ratio of SiO₂ was determined as n(NaOH)/n(SiO₂) >liquid-solid mass ratio>reaction time>reaction temperature， and the order of factors affecting the extraction ratio of B₂O₃ was reaction time>reaction temperature>n(NaOH)/n(SiO₂)>liquid-solid mass ratio. The optimum recovery conditions were n(NaOH)/n(SiO₂) of 25， reaction temperature of 50℃， reaction time of 40min， and liquid-solid mass ratio of 8. Under these conditions， the extraction ratios of SiO₂ and B₂O₃ reached 83.11% and 75.28%，respectively.

Key words: boron mud; silicon dioxide; boron oxide; sodium carbonate; sodium hydroxide

中图分类号:

TP110.9

宁志强，宋雨陶，赵润宇，韩帅男. 从硼泥中提取硅、硼的新工艺[J]. 东北大学学报（自然科学版）, 2022, 43(7): 959-965.

NING Zhi-qiang， SONG Yu-tao， ZHAO Run-yu， HAN Shuai-nan. New Technology for Extracting Silicon and Boron from Boron Mud[J]. Journal of Northeastern University(Natural Science), 2022, 43(7): 959-965.

参考文献

[1]焦森，郑厚义，屈云燕，等.全球硼矿资源供需形势分析［J］.国土资源情报，2020(10):85-89.(Jiao Sen，Zheng Hou-yi，Qu Yun-yan，et al.Supply and demand situation of global boron resources［J］.Land and Resources Information，2020(10):85-89.)
[2]尹玉霞.硼泥的环境问题及资源化利用［J］.中国资源综合利用，2020，38(2):72-75.(Yin Yu-xia.Environmental problems and comprehensive utilization of boron mud［J］.China Resources Comprehensive Utilization，2020，38(2):72-75.)
[3]Bo J，Zhang Y F，Zhang Y.Leaching magnesium oxide in boron mud by water with pressurized CO₂［J］.Hydrometallurgy，2017，171:142-148.
[4]高枫，葛颖新，刘涛，等.硫酸浸出硼泥中镁离子过程研究［J］.无机盐工业，2012，44(12):51-53.(Gao Feng，Ge Ying-xin，Liu Tao，et al.Leaching process of magnesium ion from boron slurry by sulfuric acid［J］.Inorganic Chemicals Industry，2012，44(12):51-53.)
[5]侯会丽，张广心，郑水林，等.硼泥中氧化镁组分的盐酸浸出工艺研究［J］.无机盐工业，2014，46(2):61-63，78.(Hou Hui-li，Zhang Guang-xin，Zheng Shui-lin，et al.Study on magnesium oxide leaching technology with hydrochloric acid from boron mud［J］.Inorganic Chemicals Industry，2014，46(2):61-63，78.)
[6]潘晓锋，于少明，翟龙，等.硼泥酸浸提镁过程的动力学研究［J］.矿产综合利用，2014(3):69-73.(Pan Xiao-feng，Yu Shao-ming，Zhai Long，et al.Study on kinetics of magnesium extraction from boron mud with acid leaching［J］.Multipurpose Utilization of Mineral Resources，2014(3):69-73.)
[7]Wang W，Gu H M，Zhai Y C.Study on extraction of Mg from boron mud［J］.Advanced Materials Research，2014，881/882/883:671-674.
[8]宁志强，翟玉春，周镝，等.利用硼泥制备七水硫酸镁的研究［J］.轻金属，2007(7):61-63.(Ning Zhi-qiang，Zhai Yu-chun，Zhou Di，et al.Study of the technique for the preparation of Epsom salt from the boron mud［J］.Light Metals，2007(7):61-63.)
[9]Yang X M，Hu S，Wen Y，et al.Preparation of magnesium oxide from boron mud［J］.Journal of Materials Science and Engineering，2014，32(5):727-731.
[10]范建萍.从硼泥中制取轻质氧化镁的工艺研究［J］.应用化工，1999(2):20-22.(Fan Jian-ping.Study on the technology of light magnesia extracted from boracic wastes［J］.Applied Chemical Industry，1999(2):20-22.)
[11]潘晓锋.由硼泥制取高纯氧化镁和超细球形二氧化硅的工艺研究［D］.合肥:合肥工业大学，2014.(Pan Xiao-feng.Study on the preparation of high-purity MgO and ultrafine spherical silica from boron mud［D］.Hefei:Hefei University of Technology，2014.)
[12]徐惠娟，任晓棠.碳化法从硼泥中制取轻质碳酸镁转化条件研究［J］.辽宁科技学院学报，2012，14(3):4-5，17.(Xu Hui-juan，Ren Xiao-tang.Research into the transformative condition during recovering the lightened magnesium carbonate from boronic mud with carbonizing method［J］.Journal of Liaoning Institute of Science and Technology，2012，14(3):4-5，17.)
[13]Shen R，Yang H B，Li H，et al.Preparation of magnesium carbonate trihydrate whiskers from boron mud［J］.Journal of Synthetic Crystals，2014，43(4):991-996.
[14]杨梅，陈启凡，吴晓杰.盐酸法浸取硼泥制备精制氯化镁的研究［J］.沈阳师范大学学报(自然科学版)，2016，34(2):144-147.(Yang Mei，Chen Qi-fan，Wu Xiao-jie.Preparation of refined magnesium oxide from boron sludge by via hydrochloric acid leaching method ［J］.Journal of Shenyang Normal University(Natural Science Edition)，2016，34(2):144-147.)
[15]Huang Y M，Shang J，Zhang Y P，et al.Extraction of magnesium hydroxide from boron mud by alkali melting and ammonia leaching［J］.Non-Metallic Mines，2015，38(6):45-47.
[16]杨雪梅，胡珊，王凌刚，等.利用硼泥制备氢氧化镁工艺条件研究［J］.无机盐工业，2014，46(12):57-60.(Yang Xue-mei，Hu Shan，Wang Ling-gang，et al.Research on preparing magnesium hydroxide from boron slurry［J］.Inorganic Chemicals Industry，2014，46(12):57-60.)
[17]Ning Z Q，Song Q S，Zhai Y C，et al.Desilication kinetics of calcined boron mud in molten sodium hydroxide media［J］.Journal of Central South University of Technology，2016，23(9):2191-2198.
[18]Ning Z Q，Zhai Y C，Song Q S.Extracting B₂O₃ from calcined boron mud using molten sodium hydroxide［J］.Rare Metals，2015，34(10):744-751.
[19]中华人民共和国国家质量监督检验检疫总局，中国国家标准化管理委员会.工业硅酸钠:GB/T 4209—2008［S］.北京:中国标准出版社，2008.(General Administration of Quality Supervision，Inspection and Quarantine of the People’s Republic of China，Standardization Administration of the People’s Republic of China.Sodium silicate for industrial use:GB/T 4209—2008［S］.Beijing:Standards Press of China，2008.)
[20]中华人民共和国国家质量监督检验检疫总局，中国国家标准化管理委员会.化学试剂十水合四硼酸钠(四硼酸钠):GB/T 632—2008［S］.北京:中国标准出版社，2008.(General Administration of Quality Supervision，Inspection and Quarantine of the People’s Republic of China，Standardization Administration of the People’s Republic of China.Chemical reagent-disodium tetraborate decahydrate:GB/T 632—2008［S］.Beijing:Standards Press of China，2008.)
[21]宁志强，李晓侠，翟玉春，等.硼泥的熔碱浸出脱硅［J］.东北大学学报(自然科学版)，2015，36(11):1596-1600.(Ning Zhi-qiang，Li Xiao-xia，Zhai Yu-chun，et al.Desilication of boron mud using molten sodium hydroxide media［J］.Journal of Northeastern University(Natural Science)，2015，36(11):1596-1600.)

从硼泥中提取硅、硼的新工艺

New Technology for Extracting Silicon and Boron from Boron Mud

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 0

编辑推荐

Metrics

本文评价