东北大学学报（自然科学版）

东北大学学报:自然科学版 ›› 2014, Vol. 35 ›› Issue (10): 1456-1459.DOI: 10.12068/j.issn.1005-3026.2014.10.020

• 材料与冶金 • 上一篇    下一篇

高铝粉煤灰制备氢氧化铝的比表面积及孔隙特性

张廷安1，郑朝振1，吕国志1，孙俊民2   

  1. (1 东北大学 多金属共生矿生态化利用教育部重点实验室，辽宁 沈阳 110819; 2 大唐国际发电股份有限公司 高铝煤炭资源开发利用研发中心，内蒙古 呼和浩特 010000)
  • 收稿日期:2014-04-23 修回日期:2014-04-23 出版日期:2014-10-15 发布日期:2014-05-19
  • 通讯作者: 张廷安
  • 作者简介:张廷安(1960-)，男，河南周口人，东北大学教授，博士生导师.
  • 基金资助:
    国家自然科学基金资助项目(U1202274，51204040)；教育部高校博士点专项基金资助项目(20120042110011).

Specific Surface Area and Pore Characteristics of Aluminum Hydroxide Prepared from HighAlumina Fly Ash

ZHANG Tingan1， ZHENG Chaozhen1， LYU Guozhi1， SUN Junmin2   

  1. 1. Key Laboratory of Ecological Utilization of Multimetal Intergrown Ores of Ministry of Education， Northeastern University， Shenyang 110819， China； 2. Highalumina Fly Ash Resources Development and Utilization R & D Center， Datang International Power Generation Co.， Ltd.， Hohhot 010000， China.
  • Received:2014-04-23 Revised:2014-04-23 Online:2014-10-15 Published:2014-05-19
  • Contact: ZHANG Tingan
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摘要： 以高铝粉煤灰烧结熟料为原料，经溶出、深度脱硅和分解(碳酸化分解或晶种分解)得到高白氢氧化铝，采用低温氮气吸附法分析两种分解方法制得的氢氧化铝的比表面积和孔隙分布.结果表明:氢氧化铝的等温吸附线属III类，氢氧化铝晶粒之间的孔隙以微孔为主，存在一定数量的介孔和大孔.碳分氢氧化铝BET比表面积和平均孔径远大于种分氢氧化铝，碳酸化分解时在CO2的强推动下，氢氧化铝猛烈析出并凝聚，使得晶体结构疏松，晶间空隙大.晶种分解靠晶体的长大而使晶体变粗，晶体结构致密，晶间空隙小.

关键词: 氢氧化铝, 氮吸附法, 等温线, 比表面积, 孔隙特性

Abstract: Using sintered highalumina fly ash clinker as raw material， high white aluminum hydroxide was obtained after dissolution， deep desilication and decomposition (carbonation decomposition or seed precipitation) process. Lowtemperature nitrogen adsorption method was adopted to analyze the specific surface area and pore distribution of aluminum hydroxide. The results showed that the aluminum hydroxide adsorption isotherm curve belongs to type III. Aluminum hydroxide pores most belong to micropores， and there still are some mesopores and macropores. The BET specific surface area and average pore diameter of carbonation aluminum hydroxide are much greater than those of seedprecipitation aluminum hydroxide. Driven by the strong action of CO2， aluminum hydroxide precipitates and condenses fiercely in carbonation decomposition， so the crystal structure of aluminum hydroxide is loose and intergranular pores are big. In seed precipitation， the growth of crystal makes the crystal coarsen， the structure is compact and intergranular pores are small.

Key words: aluminum hydroxide, N2 absorption method, isothermal curve, specific surface area, pore characteristics

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