真空铝热炼锂还原渣回收氢氧化铝的研究

doi:10.12068/j.issn.1005-3026.2019.04.009

东北大学学报:自然科学版 ›› 2019, Vol. 40 ›› Issue (4): 500-504.DOI: 10.12068/j.issn.1005-3026.2019.04.009

真空铝热炼锂还原渣回收氢氧化铝的研究

狄跃忠，彭建平，王耀武，冯乃祥

(东北大学冶金学院，辽宁沈阳110819)

收稿日期:2018-02-13 修回日期:2018-02-13 出版日期:2019-04-15 发布日期:2019-04-26
通讯作者: 狄跃忠
作者简介:狄跃忠(1983-)，男，山西大同人，东北大学讲师，博士；冯乃祥(1944-)，男，河北丰润人，东北大学教授.
基金资助:
国家自然科学基金资助项目(51304044，51674076，21878045)；中央高校基本科研业务费专项资金资助项目(N120302005，N162502002).

Recycle Aluminum Hydroxide from Residue of Vacuum Aluminothermic Reduction Lithium Process

DI Yue-zhong，PENG Jian-ping，WANG Yao-wu，FENG Nai-xiang

School of Metallurgy，Northeastern University，Shenyang 110819， China.

Received:2018-02-13 Revised:2018-02-13 Online:2019-04-15 Published:2019-04-26
Contact: DI Yue-zhong
About author:-
Supported by:
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摘要/Abstract

摘要： 碳酸锂、氧化铝和氧化钙混合常压煅烧可获得LiAlO₂熟料，经真空铝热还原可得金属锂，同时得到铝酸钙系还原渣，主要成分为CaO·Al₂O₃和12CaO·7Al₂O₃.为综合利用该还原渣，通过混合碱液溶出、碳酸化分解回收氢氧化铝.研究溶出温度、溶出时间、还原渣粒度、碳酸钠质量浓度、氢氧化钠质量浓度、金属锂还原率对氧化铝溶出率的影响.结果表明:以锂还原率97%的炼锂还原渣为原料，粒度分布d_○90 74μm、溶出温度95℃、溶出时间120min、碳酸钠质量浓度240g/L及氢氧化钠质量浓度8.9g/L的条件下，氧化铝的溶出率为80.73%.溶出的铝酸钠溶液经碳分可获得体积平均粒径6.50μm及白度值96.9的氢氧化铝.

关键词: 铝热还原, 还原渣, 溶出, 碳酸化分解, 氢氧化铝

Abstract: When lithium was produced in the process of aluminothermic reduction LiAlO₂ clinker in vacuum condition where the clinker was prepared by calcined mixture of lithium carbonate， alumina and calcium oxide at normal atmosphere， the reduction residue containing CaO·Al₂O₃ and 12CaO·7Al₂O₃ was obtained. In order to recycle the reduction residue， the residue was firstly leached with a mixture solution of sodium hydroxide and sodium carbonate， and then aluminum hydroxide was produced by decomposing the leaching solution with carbon dioxide. The effects of leaching temperature， leaching time， particle size， sodium carbonate concentration， sodium hydroxide concentration and lithium reduction rate on leaching rate of alumina were investigated. The results showed that the leaching rate of alumina is 80.73% under the conditions of the particle size distribution d₉₀ of 74μm，the leaching temperature of 95℃， the leaching time of 120min， the Na₂CO₃ concentration of 240g/L and NaOH concentration of 8.9g/L， when the residue is from the reduction lithium process with a reduction rate of 97%. The average particle size and the whiteness of aluminum hydroxide obtained by carbonation precipitation are 6.50μm and 96.9， respectively.

Key words: aluminothermic reduction, reduction residue, leaching, carbonation decomposition, aluminum hydroxide

中图分类号:

TF111.3

狄跃忠，彭建平，王耀武，冯乃祥. 真空铝热炼锂还原渣回收氢氧化铝的研究[J]. 东北大学学报:自然科学版, 2019, 40(4): 500-504.

DI Yue-zhong，PENG Jian-ping，WANG Yao-wu，FENG Nai-xiang. Recycle Aluminum Hydroxide from Residue of Vacuum Aluminothermic Reduction Lithium Process[J]. Journal of Northeastern University Natural Science, 2019, 40(4): 500-504.

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真空铝热炼锂还原渣回收氢氧化铝的研究

Recycle Aluminum Hydroxide from Residue of Vacuum Aluminothermic Reduction Lithium Process

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