壳聚糖/硅藻土复合材料的制备及其对Hg2+吸附

doi:10.12068/j.issn.1005-3026.2017.09.016

东北大学学报:自然科学版 ›› 2017, Vol. 38 ›› Issue (9): 1289-1292.DOI: 10.12068/j.issn.1005-3026.2017.09.016

壳聚糖/硅藻土复合材料的制备及其对Hg²⁺吸附

胡建设，张昊琳，田有粮，刘柯利

(东北大学理学院，辽宁沈阳110819)

收稿日期:2016-04-15 修回日期:2016-04-15 出版日期:2017-09-15 发布日期:2017-09-08
通讯作者: 胡建设
作者简介:胡建设( 1971-)，男，河南周口人，东北大学教授，博士生导师.
基金资助:
北京市卫生局专项重点攻关项目子课题 (2014-1-3011).

Preparation of New Chitosan/Diatomite Composite Materials and Their Adsorption Effect on Mercury Ions

HU Jian-she， ZHANG Hao-lin， TIAN You-liang， LIU Ke-li

School of Sciences， Northeastern University， Shenyang 110819， China.

Received:2016-04-15 Revised:2016-04-15 Online:2017-09-15 Published:2017-09-08
Contact: HU Jian-she
About author:-
Supported by:
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摘要/Abstract

摘要： 以硅藻土与壳聚糖为原料，戊二醛作为交联剂，制备了一种复合吸附材料，研究了其对水中Hg²⁺的吸附性能，探讨了复合吸附材料的配比、Hg²⁺初始浓度、吸附材料的质量与吸附时间等因素对Hg²⁺吸附性能的影响.研究表明，随着硅藻土含量的增加，对应Hg²⁺的吸附容量与去除率均下降;此外，随着Hg²⁺初始浓度的提高，其去除率降低，而吸附容量却提高;增加吸附剂的质量，Hg²⁺的吸附容量与去除率也相应增加;当吸附时间在45min以内，对应的吸附容量与去除率随吸附时间的增加而提高，当吸附时间超过45min后，吸附容量与去除率基本不变.

关键词: 壳聚糖, 硅藻土, 复合材料, 汞离子, 吸附作用

Abstract: A new polymer composite adsorption material of diatomite and chitosan was prepared using a crosslinking agent of glutaraldehyde and its adsorption property of mercury ions (Hg²⁺) in water was studied. The effects of the composite material ratio， initial concentration of Hg²⁺， the weight of adsorption material and adsorption time on the Hg²⁺ removal property were investigated. The results show that the Hg²⁺ removal rate and adsorption capacity decrease with the increasing diatomite content in the composite. However， the Hg²⁺ removal rate decreases and adsorption capacity increases with the increasing initial concentration of Hg²⁺. The Hg²⁺ removal rate and adsorption capacity increases with the increasing weight of the adsorption material. When the adsorption time is less than 45min， the corresponding Hg²⁺ removal rate and adsorption capacity increases with increasing adsorption time， while they become nearly constant after 45min.

Key words: chitosan, diatomite, composite material, mercury ions, adsorption effect

中图分类号:

O643.26

胡建设，张昊琳，田有粮，刘柯利. 壳聚糖/硅藻土复合材料的制备及其对Hg²⁺吸附[J]. 东北大学学报:自然科学版, 2017, 38(9): 1289-1292.

HU Jian-she， ZHANG Hao-lin， TIAN You-liang， LIU Ke-li. Preparation of New Chitosan/Diatomite Composite Materials and Their Adsorption Effect on Mercury Ions[J]. Journal of Northeastern University Natural Science, 2017, 38(9): 1289-1292.

参考文献

[1]江曙光.中国水污染现状及防治对策［J］.水产科技情报，2010，37(4):313-315.(Jiang Shu-guang.Present situation and the countermeasures of water pollution in China ［J］.Fisheries Science & Technology Information，2010，37(4):313-315.)
[2]Celik A，Demirbas A.Removal of heavy metal ions from aqueous solutions via adsorption onto modified lignin from pulping wastes ［J］.Energy Sources，2005，27(12):1167-1177.
[3]Kjellstrm T，Shiroishi K，Evrin P E.Urinary beta/sub 2/-microglobulin excretion among people exposed to cadmium in the general environment:an epidemiological study in cooperation between Japan and Sweden［J］.Environmental Research，1977，13(2):318-344.
[4]Sud D，Mahajan G，Kaur M P.Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions—a review ［J］.Bioresource Technology，2008，99(14):6017-6027.
[5]Craeye B，Geirnaert M，Schutter G D.Super absorbing polymers as an internal curing agent for mitigation of early-age cracking of high-performance concrete bridge decks［J］. Construction & Building Materials，2011，25(1):1-13.
[6]Liu D，Yuan P，Tan D，et al.Effects of inherent/enhanced solid acidity and morphology of diatomite templates on the synthesis and porosity of hierarchically porous carbon ［J］.Langmuir，2010，26(24):18624-18627.
[7]Islam M，Rahaman S，Yeum J H.Electrospun novel super-absorbent based on polysaccharide-polyvinyl alcohol-montmorillonite clay nanocomposites［J］.Carbohydrate Polymers，2015，115(8):69-77.
[8]Gerente C，Lee V K C，Le Cloirec P，et al.Application of chitosan for the removal of metals from wastewaters by adsorption—mechanisms and models review［J］.Critical Reviews in Environmental Science and Technology，2007，37(1):41-127.
[9]Crini G，Badot P M.Application of chitosan，a natural aminopolysaccharide，for dye removal from aqueous solutions by adsorption processes using batch studies:a review of recent literature［J］.Progress in Polymer Science，2008，33(4):399-447.
[10]陈洁.改性壳聚糖及其对水体重金属Cu，Cd的吸附研究［D］.浙江:浙江大学，2014.(Chen Jie.The modification of chitosan and the adsorption of heavy metal Cu，Cd water by chitosan［D］.Zhejiang:Zhejiang University，2014.)

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壳聚糖/硅藻土复合材料的制备及其对Hg²⁺吸附

Preparation of New Chitosan/Diatomite Composite Materials and Their Adsorption Effect on Mercury Ions

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