真空铝热还原炼锂新工艺中富锂熟料的制备

doi:10.3969/j.issn.1005-3026.2015.10.018

东北大学学报:自然科学版 ›› 2015, Vol. 36 ›› Issue (10): 1449-1453.DOI: 10.3969/j.issn.1005-3026.2015.10.018

真空铝热还原炼锂新工艺中富锂熟料的制备

狄跃忠，唐成伟，赵康，冯乃祥

(东北大学材料与冶金学院，辽宁沈阳110819)

收稿日期:2014-10-13 修回日期:2014-10-13 出版日期:2015-10-15 发布日期:2015-09-29
通讯作者: 狄跃忠
作者简介:狄跃忠(1983-)，男，山西大同人，东北大学讲师，博士；冯乃祥(1944-)，男，河北丰润人，东北大学教授，博士生导师.
基金资助:
国家自然科学基金资助项目(51304044)；中央高校基本科研业务费专项资金资助项目(N120302005).

Preparation of Lithium-Rich Clinker in New Vacuum Aluminothermy Reduction of Lithium Process

DI Yue-zhong， TANG Cheng-wei， ZHAO Kang， FENG Nai-xiang

School of Materials & Metallurgy， Northeastern University， Shenyang 110819， China.

Received:2014-10-13 Revised:2014-10-13 Online:2015-10-15 Published:2015-09-29
Contact: DI Yue-zhong
About author:-
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摘要/Abstract

摘要： 常压煅烧氢氧化锂、氧化铝和氧化钙混合物得到富锂熟料，真空铝热还原该熟料得到金属锂及可制备氢氧化铝的12CaO·7Al₂O₃型还原渣.研究了制团压力、煅烧温度、煅烧时间对煅烧烧损率及锂还原率的影响.结果表明:在制团压力为30MPa，煅烧温度为750~800℃，煅烧时间为60~90min的条件下，烧损率基本保持在34%左右;该条件所得富锂熟料在还原温度1100℃，还原时间90min，铝粉不过量的条件下进行真空铝热还原得到锂还原率较高.该煅烧工艺适用于真空铝热还原炼锂新工艺中富锂熟料的制备.

关键词: 氢氧化锂, 真空, 铝热还原, 烧损率, 锂还原率

Abstract: A new vacuum aluminothermy reduction of lithium process was developed， in which lithium hydroxide， alumina and calcium oxide mixture were used as raw materials. Lithium-rich clinker was prepared by calcining the mixture of raw materials. Metal lithium and reduction slag contained the 12CaO·7Al₂O₃ which was used to form aluminum hydroxide were produced by the vacuum aluminothermy reduction process. Effects of briquette pressure， calcination temperature and time on the burning loss rate and lithium reduction rate were investigated. The result showed that the burning loss rate remained about 34% under the conditions of briquette pressure 30MPa， calcination temperature 750~800℃ and calcination time 60~90min. The lithium reduction rate was relatively high when the lithium-rich clinker obtained under the above conditions were used to vacuum aluminothermy reduction under the conditions of reduction temperature 1100℃， reduction time 90min and theoretical aluminum addition mass. This kind of calcination process was suitable to the preparation of lithium-rich clinker for the new vacuum aluminothermy reduction of lithium.

Key words: lithium hydroxide, vacuum, aluminothermic reduction, burning loss rate, lithium reduction rate

中图分类号:

TF826.3

狄跃忠，唐成伟，赵康，冯乃祥. 真空铝热还原炼锂新工艺中富锂熟料的制备[J]. 东北大学学报:自然科学版, 2015, 36(10): 1449-1453.

DI Yue-zhong， TANG Cheng-wei， ZHAO Kang， FENG Nai-xiang. Preparation of Lithium-Rich Clinker in New Vacuum Aluminothermy Reduction of Lithium Process[J]. Journal of Northeastern University:Natural Science, 2015, 36(10): 1449-1453.

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真空铝热还原炼锂新工艺中富锂熟料的制备

Preparation of Lithium-Rich Clinker in New Vacuum Aluminothermy Reduction of Lithium Process

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