Effect of Metallic Minerals on Transport Characteristics of Ammonium Dibutyl Dithiophosphate in Saturated Porous Media

doi:10.12068/j.issn.1005-3026.2024.03.012

Abstract

Abstract:

Taking ammonium dibutyl dithiophosphate（ADD） as the research object， based on the saturated soil column migration experiment and mathematical model， the effects of the type and amount of metal loading on the surface of quartz sand on the migration law of ADD were explored. The results show that the migration of ADD is not affected by the loading of goethite on the surface of quartz sand （iron content 0.028% and 0.042%）. However， when CuO was coated on sand surface subsequently， ADD reacted with Cu²⁺ on the surface of the minerals， forming Cu?ADD complex， which restrained the transport of ADD. With the increase of copper content from 0.001 8% to 0.005 5%， the recovery rate of ADD decreased from 44.32% to 8.85%. When the copper content is 0.001 8%， the recovery rate increases to 63.64% as the mass concentration of ADD increases from 20 mg/L to 60 mg/L.

Key words: ammonium dibutyl dithiophosphate, goethite, copper oxide, transport, mathematic model

CLC Number:

X 53

Yu-ting FENG, Li CHENG, Ke-mei WANG, En-zhu HU. Effect of Metallic Minerals on Transport Characteristics of Ammonium Dibutyl Dithiophosphate in Saturated Porous Media[J]. Journal of Northeastern University(Natural Science), 2024, 45(3): 401-406.

Figures/Tables 6

Table 1 Soil column transport experiment of ammonium dibutyl dithiophosphate

名称	介质种类	w(Fe)/%	w(Cu)/%	ADD质量浓度
名称	介质种类	w(Fe)/%	w(Cu)/%	mg·L^–1
CK	石英砂	—	—	60
F1H	覆铁砂Ⅰ	0.042	<0.000 1	60
F1L	覆铁砂Ⅰ	0.042	<0.000 1	20
F2L	覆铁砂Ⅱ	0.028	<0.000 1	20
C1H	覆铁铜砂Ⅰ	0.039	0.001 8	60
C1L	覆铁铜砂Ⅰ	0.039	0.001 8	20
C2L	覆铁铜砂Ⅱ	0.040	0.005 5	20

Fig.1 Breakthrough curves of ammonium dibutyl dithiophosphate （60 mg/L） transport in CK， F1H and C1H

Table 2 The peak value and recovery rate for breakthrough curves of ammonium dibutyl dithiophosphate transport

参数	CK	F1H	C1H	F2L	C1L	F1L	C2L
ρ/ρ₀峰值	0.99	0.96	0.76	0.99	0.64	1.03	0.20
回收率/%	99.65	95.61	63.64	97.82	44.32	104.07	8.85

Table 3 The model fitting results for breakthrough curves of ammonium dibutyl dithiophosphate transport

模型	参数	CK	F1H	C1H	F2L	C1L	F1L	C2L
ES	K_d/(cm³·g^-1)	0.062	0.079	—	0.088	—	0.066	—
	R²	0.978	0.964	—	0.960	—	0.968	—
	RMSE	0.029	0.041	—	0.039	—	0.032	—
	AIC	-240.80	-222.20	—	-226.10	—	-239.90	—
TS	f	0.420	0.013	0.004	0.018	0.003	0.025	0.013
	K_d/(cm³·g^-1)	0.140	6.024	77.165	4.787	161.120	2.642	19.011
	ω	1.86×10^-3	5.14×10^-5	2.07×10^-5	4.60×10^-5	1.71×10^-5	3.44×10^-5	5.26×10^-4
	R²	0.977	0.964	0.812	0.960	0.710	0.968	0.290
	RMSE	0.029	0.033	0.075	0.035	0.093	0.031	0.145
	AIC	-238.10	-234.50	-176.70	-230.10	-160.90	-237.80	-130.40
TK	k_a²/min^-1	—	—	0.020	—	0.034	—	0.129
	$S m a x 1$ /(μg·g^-1)	—	—	0.321	—	0.528	—	0.279
	k_a¹/min^-1	—	—	0.167	—	0.192	—	0.657
	k_d¹/min^-1	—	—	0.009	—	0.012	—	0.014
	R²	—	—	0.966	—	0.901	—	0.547
	RMSE	—	—	0.032	—	0.055	—	0.125
	AIC	—	—	-232.90	—	-196.30	—	-138.70

Table 3 The model fitting results for breakthrough curves of ammonium dibutyl dithiophosphate transport

模型	参数	CK	F1H	C1H	F2L	C1L	F1L	C2L
ES	K_d/(cm³·g^-1)	0.062	0.079	—	0.088	—	0.066	—
	R²	0.978	0.964	—	0.960	—	0.968	—
	RMSE	0.029	0.041	—	0.039	—	0.032	—
	AIC	-240.80	-222.20	—	-226.10	—	-239.90	—
TS	f	0.420	0.013	0.004	0.018	0.003	0.025	0.013
	K_d/(cm³·g^-1)	0.140	6.024	77.165	4.787	161.120	2.642	19.011
	ω	1.86×10^-3	5.14×10^-5	2.07×10^-5	4.60×10^-5	1.71×10^-5	3.44×10^-5	5.26×10^-4
	R²	0.977	0.964	0.812	0.960	0.710	0.968	0.290
	RMSE	0.029	0.033	0.075	0.035	0.093	0.031	0.145
	AIC	-238.10	-234.50	-176.70	-230.10	-160.90	-237.80	-130.40
TK	k_a²/min^-1	—	—	0.020	—	0.034	—	0.129
	$S m a x 1$ /(μg·g^-1)	—	—	0.321	—	0.528	—	0.279
	k_a¹/min^-1	—	—	0.167	—	0.192	—	0.657
	k_d¹/min^-1	—	—	0.009	—	0.012	—	0.014
	R²	—	—	0.966	—	0.901	—	0.547
	RMSE	—	—	0.032	—	0.055	—	0.125
	AIC	—	—	-232.90	—	-196.30	—	-138.70

Fig.2 Breakthrough curves of ammonium dibutyl dithiophosphate with various initial concentrations in F1H，F1L and C1H，C1L

Fig.3 Breakthrough curves of ammonium dibutyl dithiophosphate （20 mg/L） in quartz sand with different metal loadings

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