Journal of Northeastern University Natural Science ›› 2016, Vol. 37 ›› Issue (12): 1740-1744.DOI: 10.12068/j.issn.1005-3026.2016.12.015

• Materials & Metallurgy • Previous Articles     Next Articles

High Temperature Modification on Coconut Shell Activated Carbon and Adsorptivity of the Activated Carbon for K+ in Aluminum Electrolyte

HOU Jian-feng, WANG Zhao-wen, LI Tuo-fu, SHI Zhong-ning   

  1. School of Metallurgy, Northeastern University, Shenyang 110819, China.
  • Received:2015-01-18 Revised:2015-01-18 Online:2016-12-15 Published:2016-12-23
  • Contact: WANG Zhao-wen
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Abstract: According to kinetic calculation of adsorption K+ using coconut activated carbon in molten aluminum electrolyte, the modification of the surface properties and the capacity of removing potassium (K+) using the high-temperature modified cocoanut activated carbon were studied, associated with the analysis of SEM, ASAP2000M and FTIR spectrometer. The results showed that the specific surface area changed from 918m2/g to 2544 m2/g after high-temperature modification and the pore size distribution of the adsorbent which exhibited the uniform mesopores were optimized. Meanwhile, the functional group species of activated carbon were not changed after high-temperature modification, which indicated that the structure of high-temperature modification activated carbon could keep stable in molten aluminum electrolyte. For the capacity of removing K+, it was found that the adsorption kinetics process could be described using the pseudo-second-order model and the adsorption equilibrium was reached after 35 minutes with the maximum adsorption capacity of K+ of 20.8mg/g.

Key words: high temperature modification, coconut activated carbon, aluminum electrolyte, potassium; adsorption

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