Journal of Northeastern University Natural Science ›› 2018, Vol. 39 ›› Issue (1): 35-39.DOI: 10.12068/j.issn.1005-3026.2018.01.008

• Materials & Metallurgy • Previous Articles     Next Articles

Effect of Mg, Ca Addition on Microstructure and Properties of Biodegradable Zn Alloy

WANG Li-qing1,2, SUN Shi-neng1,2, REN Yu-ping1,2, QIN Gao-wu1,2   

  1. 1. School of Materials Science & Engineering, Northeastern University, Shenyang 110819, China; 2. Key Laboratory for Anisotropy and Texture of Materials
  • Received:2016-08-08 Revised:2016-08-08 Online:2018-01-15 Published:2018-01-31
  • Contact: QIN Gao-wu
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Abstract: Pure Zn and Zn-0.2Mg-xCa (x=0, 0.06, 0.15 and 0.3,mass fraction) alloys were prepared by indirect hot extrusion. The microstructure, mechanical properties and in vitro degradation rate of extruded Zn-based alloys were investigated by X-ray diffraction, scanning electron microscopy, optical microscope, tensile test and immersion test. The results showed that pure Zn consisted of equiaxed grains with the size of 100μm and Zn-0.2Mg-xCa alloys were composed of refined grains with the size of 15~20μm and the second phases of Mg2Zn11 and CaZn13. With increasing Ca addition, the amount of CaZn13 increased and the size of CaZn13 reached 15~50μm when the Ca mass fraction was over 0.15%. The yield strength and elongation of pure Zn was 64MPa and 14%, respectively. With increasing Ca addition, the yield strength of Zn-0.2Mg-xCa increased from 180MPa to 200MPa, while the elongation decreased from 18% to 6%. The degradation rate of Zn and Zn-0.2Mg-xCa kept between 0.05~0.15mm·a-1 and decreased with Ca addition.

Key words: Zn-Mg-Ca alloys, indirect hot extrusion, microstructure, mechanical property, degradation rate

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