Journal of Northeastern University Natural Science ›› 2020, Vol. 41 ›› Issue (9): 1321-1327.DOI: 10.12068/j.issn.1005-3026.2020.09.018

• Resources & Civil Engineering • Previous Articles     Next Articles

Effect of CO2/N2 Dilution on the Propagation of Laminar Flames of H2/CH4

SHANG Rong-xue1, GAO Jun-hao1,2, YANG Yue1, LI Gang1   

  1. 1. School of Resources & Civil Engineering, Northeastern University, Shenyang 110819, China; 2. State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230027, China.
  • Received:2019-11-28 Revised:2019-11-28 Online:2020-09-15 Published:2020-09-15
  • Contact: SHANG Rong-xue
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Abstract: The transmission speeds of laminar flames of H2/CH4/air mixtures with CO2/N2 dilution were experimentally studied using the Bunsen burner method incorporating the schlieren technique. To thoroughly investigate the diluted effect of CO2/N2 on laminar premixed flames of H2/CH4/air mixtures, the adiabatic flame temperatures, sensitivities of the mixtures with various CO2/N2 dilution ratios and the mole fractions of vital radicals were calculated using GRI-3.0 mechanism. The research results showed that GRI-3.0 mechanism provided better estimates of the transmission speeds of hythane flames; laminar flame speeds and adiabatic flame temperatures decreased with the growth of CO2/N2 dilution ratios. Compared with N2, CO2 presented the stronger thermal effect and chemical kinetics effect on the decrease of the laminar flame speeds of diluted hythane. With the increase of CO2 dilution ratios, the dominant promotion of the oxidation reaction H+O2O+OH on the mass burning rates of mixtures can be inhibited by the significant reductions of H radicals. Therefore, the laminar flame speed of mixtures remarkable decreased with the growth of CO2 rations.

Key words: Bunsen burner, laminar flame speed, CO2/N2 dilution, sensitivity analysis, vital radical

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