东北大学学报（自然科学版）

东北大学学报(自然科学版) ›› 2013, Vol. 34 ›› Issue (9): 1282-1286.DOI: -

• 材料与冶金 • 上一篇    下一篇

分段法研究烧结矿还原的动力学过程

赵勇1，吴铿1，潘文1,2，刘起航1   

  1. (1.北京科技大学钢铁冶金新技术国家重点实验室，北京100083；2.首钢技术研究院，北京100041)
  • 收稿日期:2013-03-29 修回日期:2013-03-29 出版日期:2013-09-15 发布日期:2013-04-22
  • 通讯作者: 赵勇
  • 作者简介:赵勇(1979-)，男，吉林通化人，北京科技大学博士研究生；吴铿(1951-)，男，辽宁鞍山人，北京科技大学教授，博士生导师.
  • 基金资助:
    国家自然科学基金资助项目(51274026，50934007)；国家高技术研究发展计划项目(2009AA06Z105).

Investigation of the Reduction Kinetics Process of Sinter Ore by Sectional Stepwise Method

ZHAO Yong1， WU Keng1， PAN Wen1,2， LIU Qihang1   

  1. 1. State Key Laboratory of Advanced Metallurgy， University of Science and Technology Beijing， Beijing 100083， China; 2. Shougang Research Institute of Technology， Beijing 100041， China.
  • Received:2013-03-29 Revised:2013-03-29 Online:2013-09-15 Published:2013-04-22
  • Contact: WU Keng
  • About author:-
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摘要： 根据工业生产烧结矿的还原动力学特点，从冶金传输原理的质量传输和化学反应的基本原理出发，针对还原过程中的不同阶段分别建立了立方体颗粒的化学反应过程动力学和分子扩散过程的新模型.在所建立模型的基础上采用分段法研究了CO还原烧结矿的反应过程动力学，得出不同限速性环节转换的时间点和相关的动力学参数，进而给出了动力学参数与温度的关系式.通过对工业生产烧结矿还原过程中的微观结构变化的观察验证了该模型对不同限速环节判断的准确性及其合理性.采用分段法可以确定出不同控制环节的转换时间点和动力学参数可以普适地用在其他反应过程动力学的研究中.

关键词: 反应过程动力学, 分段法, 烧结矿, 动力学参数, 立方体

Abstract: According to the reduction kinetics characteristics of industrial production of sinter， a new model concerned chemical reduction kinetics and molecular diffusion of the cubic particles in different states of reduction process was established on the basis of mass transfer of metallurgy transport principle and the basic principle of the chemical reduction. The sectional stepwise method was adopted to study the reaction kinetics of the sinter particles reduced by CO. Then the switch point of the different ratelimiting steps and the relevant kinetic parameters were obtained. Finally， the relationship between the kinetic parameters and temperature was determined. Moreover， the accuracy of distinguishing different ratelimiting steps of this model and its rationality was verified through the observation of the microstructure evolution during the reduction process of sinter ores. Therefore， the sectional stepwise method determined the switch point of different ratelimiting steps and the relevant kinetic parameters， which can be universally used in the investigations of dynamics of other reaction process.

Key words: reaction kinetics, sectional stepwise method, sinter ore, kinetic parameters, cube

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