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Synthesis and magnetization characteristics of Fe3O4 nanoparticles
Shen, Yong-Feng (1); Zhou, Fang (1); Wang, Yan-Dong (1); Zuo, Liang (1)
2009, 30 (4):
555-558.
DOI: -
The effect of preparation process on the particle sizes and magnetization characteristics of Fe3O4 nanoparticles was characterized by XRD, high-energy XRD, TEM and vibrating sample magnetometer. It was indicated that the average particle size is 32 nm and 7 nm as the results of polyol method and co-precipitation process, respectively. The powdered Fe3O4 nanoparticle samples prepared by two methods showed that the saturated magnetization, remanent magnetization Mr, coercive force Hc are 6.8 × 10-3 A/m (8% lower than that of bulk samples), 4.2 × 10-3 A/m, 1.43 × 10-2 T and 3.3 × 10-4 A/m (about 96% lower than that of bulk samples), 0.0 A/m, 0.0 T, respectively. All these reveal that the size effect causes the occurrence of superparamagnetism, and that the particle size and magnetization characteristics of powdered Fe3O4 relate closely to its preparation process.
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