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Stability of the ternary complexes of Pd(II)-phenylimid-l,10-phenanthroline-amino acid
Sun, Ya-Guang (1); Wei, De-Zhou (1); Gao, En-Jun (2); Wang, Chuan-Sheng (2)
2003, 24 (11):
1088-1091.
DOI: -
The stability constant lgK and relevant characteristic constants ΔlgK and lgX of ternary complexes of Pd(PIP) (Aa)+ were determined by pH potential titration at 37°C with μ(ionic strength)=0.1 (KNO3) in the mixed medium of ethanol/H2O of which the ethanol volume ratio was 10%, 20%, 30%, 40% or 50% individually each time, Where PIP=Phenylimid-1,10-Phenanthroline was taken as the 1st ligand and Aa-=gly-, phe- and leu- as the 2nd one. The results show that lgK≥14 which implies that there is very strong bond in the ternary complexes, and that both ΔlgK and lgX are greater than the statistical expected value, which mean there is extra stability in the ternary complexes. The contributing ratio of electronic effect and hydrophobia effect (aromatic nucleus stacking) in extra stability was calculated. The results show that when the volume ratio of ethanol is 30%, hydrophobic effect (aromatic nucleus stacking) comes to its maximum value.
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