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Effect of CaO on crystallization behavior of CaO-Al2O3-SiO2 system glass ceramics
Shi, Pei-Yang (1); Jiang, Mao-Fa (1); Liu, Cheng-Jun (1); Wang, De-Yong (1)
2004, 25 (9):
866-869.
DOI: -
Several glass ceramics of CaO-Al2O3-SiO2 system were prepared via sintering process and investigated by means of DTA, XRD and SEM, based on crystallization kinetics. The activation energy E, for the crystallization transform of such glasses are calculated by Kissinger equation, and it is found that the activation energy decreases with increasing CaO content and decreasing crystallization temperature. As a result, an inference is drawn that the system is integrally crystallized if the characteristic parameter n=2. Experimental results reveal that the crystallization phase of such glasses are all of wollastonite, and the increasing CaO content is beneficial to the further crystallization of glass ceramic. But, at the same time, it brings more obvious defects to glass surface, such as pits, outshoots and cracks.
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