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Compositional analysis of neutralized water through bio-oxidation for refractory gold ores
Yang, Hong-Ying (1); Gong, En-Pu (2); Chen, Gang (1); Zi, Jian-Wei (2)
2004, 25 (12):
1173-1175.
DOI: -
Chemical analysis and X-ray powder crystal analysis were made to neutralized water and crystallization contained in it. It was found that there are a large amount of substances containing magnesium, potassium, sodium and calcium in neutralized water, of which the crystallization is mainly in form of sulphates including MgSO4·3H2O, MgSO4·4H2O, MgSO4·1.25H2O and CaSO4·2H2O. Such a large amount of magnesium sulphates or calcium sulphate come from two processes. One is the bio-oxidation in which the mineral composition of the gold ore used is complicate with many carbonates/silicates bearing magnesium/calcium and part of them dissolve into the solution cumulatively. The other is the neutralization using limestone, after which the residual calcium deposits in the solution. Neutralized water always cause the water pipeline to jam up when it is used cyclically in bio-oxidation process because of the high-concentration magnesium/calcium and, at the same time, the high-concentration magnesium will suppress the growth of bioleaching bacteria then result in adverse effect on bio-oxidation process.
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