Effect of w(Fe)/w(Ni) Ratio on Mo2FeB2 Based Cermet
LIU Jun-ru, ZHANG Guo-hua, ZHOU Guo-zhi
2023, 44 (9):
1269-1278.
DOI: 10.12068/j.issn.1005-3026.2023.09.007
Mo2FeB2 based cermets with different w(Fe)/w(Ni)(10∶0, 7∶3, 5∶5, 3∶7) were prepared by the vacuum liquid phase sintering with MoB, Fe, Ni, and Cr powders as raw materials. The effects of w(Fe)/w(Ni) on the phase compositions, microstructures and mechanical properties of cermets were investigated. The results showed that the compositions of hard and binder phases of boride-based cermet with different w(Fe)/w(Ni) were different. When w(Fe)/w(Ni) of 3∶7, the hard phase was composed of Mo2NiB2 and Mo2FeB2; while in the cases of other w(Fe)/w(Ni), the hard phase was Mo2FeB2. At 1350℃, the microstructure of cermets was uniform and the size of pore is minimized, with the increase of sintering temperature, the hard-phase particles aggregated and the microstructure was not homogeneous, which led to the decrease of mechanical properties. After sintering at 1350℃ for 2h, the hardness and bending strength of the obtained cermet(w(Fe)/w(Ni)=10∶0) reached the maximum, which were 82.1 HRA and 1498.7MPa respectively. Meanwhile, the analysis of fracture morphology revealed that a large number of dimples and rich tearing edges are closely related to the improvement of the bending strength of cermets.
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