25%K2O-30%Na2O-45%SiO2熔渣中超声空化行为的数值模拟

doi:10.12068/j.issn.1005-3026.2023.11.010

摘要/Abstract

摘要： 为了明晰熔渣体系中超声的空化行为，应用Rayleigh-Plesset方程模拟1020℃条件下25%K₂O-30%Na₂O-45%SiO₂熔渣中空化泡的运动行为.结果表明，在空化核尺寸15μm，声压振幅3.039MPa的条件下，空化泡在频率25kHz由一次振荡溃灭变为多次振荡才溃灭的瞬态空化，36kHz变为无周期稳态空化，63kHz变成周期稳态空化，呈现振幅降低和溃灭时间变长的特点.在空化核尺寸15μm，频率20kHz 的条件下，空化泡在声压2.4MPa处由稳态空化变为一次振荡溃灭的瞬态空化，17MPa处变为2次振荡溃灭的瞬态空化， 170MPa处变为多次振荡才溃灭的瞬态空化，呈现振幅增大和溃灭时间变长的特点.在声压振幅3.039MPa，频率20kHz的条件下，空化泡在空化核2μm由稳态空化变为一次振荡溃灭空化，21μm 变为多次振荡才溃灭的空化，33μm变为非周期稳态空化，呈现振幅降低和溃灭时间变长的特点.

关键词: 熔渣；超声；空化；数值模拟

Abstract: To clarify the cavitation behavior of ultrasonic in the slag system， the Rayleigh-Plesset equation was applied to simulate the motion behavior of cavitation bubbles in the 25% K₂O-30% Na₂O-45% SiO₂ slag at 1020℃. The results show that at the cavitation nucleus of 15μm and the sound pressure of 3.039MPa， the cavitation bubbles change from one oscillation collapse to transient cavitation with multiple oscillations before collapse at 25kHz， to acyclic steady-state cavitation at 36kHz， and to periodic steady-state cavitation at 63kHz， showing an overall decrease in vibration amplitude and increase in collapse time. At cavitation nucleus of 15μm and frequency of 20kHz， the cavitation bubble changes from steady-state cavitation to one-oscillation collapse transient cavitation at 2.4MPa， to two-oscillation collapse transient cavitation at 17MPa， and to multi-oscillation collapse transient cavitation at 170MPa， showing an overall increase in vibration amplitude and collapse time. At sound pressure of 3.039MPa and frequency of 20kHz， the cavitation bubble changed from periodic steady-state cavitation to one-oscillation collapse transient cavitation at 2μm， then to multi-oscillation collapse transient cavitation at 21μm， and finally to acyclic steady-state cavitation at 33μm， showing an overall decrease in vibration amplitude and an increase in collapse time.

Key words: metallurgical slag; ultrasound; cavitation; numerical simulation

中图分类号:

焦石岩，廖相巍，闵义，刘承军. 25%K₂O-30%Na₂O-45%SiO₂熔渣中超声空化行为的数值模拟[J]. 东北大学学报（自然科学版）, 2023, 44(11): 1584-1590.

JIAO Shi-yan， LIAO Xiang-wei， MIN Yi， LIU Cheng-jun. Numerical Simulation of Ultrasonic Cavitation Behavior in 25%K₂O-30%Na₂O-45%SiO₂ Slag[J]. Journal of Northeastern University(Natural Science), 2023, 44(11): 1584-1590.

参考文献

[1]朱立光，王杏娟.连铸保护渣理论与实践［M］.北京:冶金工业出版社，2015:174.(Zhu Li-guang，Wang Xing-juan.Theories and application of continuous casting mold fluxes［M］.Beijing:Metallurgical Industry Press，2015:174.)
[2]Min Y，Luo J，Liu C J.Viscosity and related structure transformation of fluorine bearing silicate melt under ultrasonic field［J］.Ultrasonics Sonochemistry，2019，55(6):289-296.
[3]Min Y，Jiao S Y，Zhang R，et al.Surface tension and related ions behavior of silicate melts of the Na₂O-K₂O-SiO₂-CaF₂ system under ultrasonic irradiation［J］.ISIJ International，2021，61(3):1022-1028.
[4]Eskin G I，Eskin D G.Production of natural and synthesized aluminum-based composite materials with the aid of ultrasonic(cavitation)treatment of the melt［J］.Ultrasonics Sonochemistry，2003，10(4):297-301.
[5]Fox A B，Valdez M E，Gisby J，et al.Dissolution of ZrO₂，Al₂O₃，MgO and MgAl₂O₄ particles in a B₂O₃ containing commercial fluoride-free mould slag［J］.ISIJ International，2004，44(5):836-845.
[6]Price G J，White A J，Clifton A A.The effect of high-intensity ultrasound on solid polymers［J］.Polymer，1995，36(26):4919-4925.
[7]Madras G，Chattopadhyay S.Effect of solvent on the ultrasonic degradation of poly(vinyl acetate)［J］.Polymer Degradation and Stability，2001，71(2):273-278.
[8]Eskin G I.Broad prospects for commercial application of the ultrasonic(cavitation)melt treatment of light alloys［J］.Ultrasonics Sonochemistry，2001，8(3):319-325.
[9]Kang J W，Zhang X P，Wang S，et al.The comparison of ultrasonic effects in different metal melts［J］.Ultrasonics，2015，57:11-17.
[10]Qu W X，Xie Y H，Shen Y，et al.Simulation on the effects of various factors on the motion of ultrasonic cavitation bubble［J］.Mathematical Modelling of Engineering Problems，2017，4(4):173-178.
[11]应崇福.超声学［M］.北京:科学出版社，1990:15.(Ying Chong-fu.Ultrasonics ［M］.Beijing:Science Press，1990:15.)
[12]Lee J H，Tey W Y，Lee K M，et al.Numerical simulation on ultrasonic cavitation due to superposition of acoustic waves［J］.Materials Science for Energy Technologies，2020，3:593-600.
[13]冯若.超声手册［M］.南京:南京大学出版社，1999:20.(Feng Ruo.Handbook of ultrasound ［M］.Nanjing:Nanjing University Press，1999:20.)
[14]Chen X S，Jiao Q B，Tan X，et al.Numerical simulation of ultrasonic enhancement by acoustic streaming and thermal effect on mass transfer through a new computation model［J］.International Journal of Heat and Mass Transfer，2021，171:121074.
[15]朱哲民，龚秀芬，杜功焕.声学基础［M］.上海:上海科学技术出版社，1981:180.(Zhu Zhe-min，Gong Xiu-fen，Du Gong-huan.Fundamentals of acoustics ［M］.Shanghai:Shanghai Science and Technology Press，1981:180.)
[16]李争彩，林书玉.超声空化影响因素的数值模拟研究［J］.陕西师范大学学报(自然科学版)，2008，36(1):38-42.(Li Zheng-cai，Lin Shu-yu.Numerical simulation of the factors influencing ultrasonic cavitation［J］.Journal of Shaanxi Normal University(Natural Science Edition)，2008，36(1):38-42.)
[17]Liu L Y，Yang Y，Liu P H，et al.The influence of air content in water on ultrasonic cavitation field［J］.Ultrasonics Sonochemistry，2014，21(2):566-571.
[18]许英强.连铸保护渣技术问答［M］.北京:冶金工业出版社，2013:68.(Xu Ying-qiang.Questions and answers on slag protection technology for continuous casting ［M］.Beijing:Metallurgical Industry Press，2013:68.)
[19]Yu X，Pomfret R J，Coley K S.Dissolution of alumina in mold fluxes［J］.Metallurgical and Materials Transactions B，1997，28(2):275-279.
[20]李杰，陈伟庆，何北星，等.超声波处理高温钢液的工具头材质研究［J］.北京科技大学学报，2007，29(12):1246-1249.(Li Jie，Chen Wei-qing，He Bei-xing，et al.Ultrasonic treatment of high-temperature steel for tool head material research［J］.Journal of University of Science and Technology Beijing，2007，29(12):1246-1249.)
[21]张鹏利.超声空化多泡及其辐射声场的研究［D］.西安:陕西师范大学，2010.(Zhang Peng-li.Study on ultrasonic cavitation multi-bubbles and their radiated sound field ［D］.Xi’an:Shaanxi Normal University，2010.)
[22]赵世琏.铝合金超声半连铸结晶器熔池流场数值模拟及试验研究［D］.长沙:中南大学，2010.(Zhao Shi-lian.Numerical simulation and experimental study on the flow field of the melt pool of aluminum alloy ultrasonic semi-continuous crystallizer ［D］.Changsha:Central South University，2010.)
[23]曹京京.基于酯交换反应中超声空化的数值模拟［D］.镇江:江苏大学，2013.(Cao Jing-jing.Numerical simulation of ultrasonic cavitation based on transesterification［D］.Zhenjiang:Jiangsu University，2013.)(上接第1583页)
[8]Ueji R，Tsuji N，Minamino Y，et al.Effect of rolling reduction on ultrafine grained structure and mechanical properties of low-carbon steel thermomechanically processed from martensite starting structure［J］.Science & Technology of Advanced Materials，2004，5(1):153-162.
[9]Ueji R，Tsuji N，Minamino Y，et al.Ultragrain refinement of plain low carbon steel by cold-rolling and annealing of martensite［J］.Acta Materialia，2002，50(16):4177-4189.
[10]Zhao L J，Park N，Tian Y Z，et al.Novel thermomechanical processing methods for achieving ultragrain refinement of low-carbon steel without heavy plastic deformation［J］.Materials Research Letters，2017，5(1):61-68.
[11]Yuan Q，Xu G，Liu M，et al.Effects of rolling temperature on the microstructure and mechanical properties in an ultrafine grained low-carbon steel［J］.Steel Research International，2019，90(2):1800318.
[12]Azizi H，Zurob H S，Embury D，et al.Using architectured materials to control localized shear fracture［J］.Acta Materialia，2018，143:298-305.
[13]王国栋.新一代控制轧制和控制冷却技术与创新的热轧过程［J］.东北大学学报(自然科学版)，2009，30(7):913-922.(Wang Guo-dong.New generation TMCP and innovative hot rolling process［J］.Journal of Northeastern University(Natural Science)，2009，30(7):913-922.)
[14]Zhang Q X，Yuan Q，Wang Z T，et al.Enhanced mechanical properties in a low-carbon ultrafine grain steel by niobium addition［J］.Metallurgical and Materials Transactions A，2021，52(11):5123-5132.
[15]刘理，徐晓宁.异构纳米/超细晶钢的研究进展［J］.轧钢，2021，38(5):70-74.(Liu Li，Xu Xiao-ning.Research on heterogeneous nano/ultrafine grained steel［J］.Steel Rolling，2021，38(5):70-74.)
[16]Han D T，Xu Y B，Zhang J Y，et al.Relationship between crystallographic orientation，microstructure characteristic and mechanical properties in cold rolled 3.5Mn TRIP steel［J］.Materials Science and Engineering:A，2021，821:141625.
[17]Kang Y L，Han Q H，Zhao X M，et al.Influence of nanoparticle reinforcements on the strengthening mechanisms of an ultrafine-grained dual phase steel containing titanium［J］.Materials & Design，2013，44(2):331-339.
[18]Li C N，Yuan G，Ji F Q，et al.Mechanism of microstructural control and mechanical properties in hot rolled plain C-Mn steel during controlled cooling［J］.ISIJ International，2015，55(8):1721-1729.
[19]Liang Z Y，Li Y Z，Huang M X.The respective hardening contributions of dislocations and twins to the flow stress of a twinning-induced plasticity steel［J］.Scripta Materialia，2016，112:28-31.
[20]Liu Y F，Cao Y，Mao Q Z，et al.Critical microstructures and defects in heterostructured materials and their effects on mechanical properties［J］.Acta Materialia，2020，189(5):129-144.

25%K₂O-30%Na₂O-45%SiO₂熔渣中超声空化行为的数值模拟

Numerical Simulation of Ultrasonic Cavitation Behavior in 25%K₂O-30%Na₂O-45%SiO₂ Slag

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	刘兴刚，王亚琴，马召俊，张德良. 挤压锻温度对固态再生H11钢组织和性能的影响[J]. 东北大学学报:自然科学版, 2020, 41(10): 1394-1401.
[2]	王卓，李宝宽，刘中秋，牛冉. 垂直连铸凝固过程的数值模拟研究[J]. 东北大学学报:自然科学版, 2020, 41(9): 1257-1261.
[3]	苏建铭，豆志河，张廷安，刘燕. 氧质量分数对于镁蒸气铁水脱硫的影响[J]. 东北大学学报:自然科学版, 2020, 41(6): 824-827.
[4]	张晓博，刘承军，姜茂发. CaF₂对CaO-Al₂O₃-CaF₂熔体结构影响的分子动力学研究[J]. 东北大学学报:自然科学版, 2020, 41(4): 510-515.
[5]	李阳，陈常勇，秦国清，姜周华. 坩埚材质对55SiCr弹簧钢中夹杂物的影响[J]. 东北大学学报:自然科学版, 2020, 41(2): 200-207.
[6]	李一明，李宝宽，齐凤升. 火焰清理工艺中平行多孔射流非预混燃烧的研究[J]. 东北大学学报:自然科学版, 2019, 40(4): 505-509.
[7]	高彩茹，刘宝喜，潘欢，高秀华. 高韧性420MPa级桥梁钢开发及强化机制分析[J]. 东北大学学报:自然科学版, 2018, 39(8): 1123-1126.
[8]	勾大钊，雷洪，耿佃桥. 电磁搅拌钢包内气泡聚并破裂行为[J]. 东北大学学报:自然科学版, 2018, 39(5): 633-637.
[9]	勾大钊，王伟先，耿佃桥，雷洪. 吹氩钢包内气泡聚并破碎和运动行为[J]. 东北大学学报:自然科学版, 2018, 39(2): 195-199.
[10]	张涛，聂海棋，罗志国，邹宗树. 连铸结晶器内气泡运动行为及影响因素[J]. 东北大学学报:自然科学版, 2018, 39(1): 61-65.
[11]	程中福，朱苗勇. 钢包底喷粉元件狭缝粗糙壁面对粉气流输送行为影响[J]. 东北大学学报:自然科学版, 2017, 38(9): 1262-1267.
[12]	王安国，姜周华，娄延春，熊云龙. 空心环形件电渣熔铸内结晶器的对流换热系数[J]. 东北大学学报:自然科学版, 2017, 38(8): 1093-1098.
[13]	李阳，李亮，陈圆圆，邓安元. 侧壁式感应加热中间包磁/热/流耦合模拟[J]. 东北大学学报:自然科学版, 2017, 38(7): 966-971.
[14]	刘中秋，李宝宽. 连铸结晶器内偏流及漩涡卷渣的实验研究[J]. 东北大学学报:自然科学版, 2017, 38(5): 666-670.
[15]	郭庆清，王佳亮，吴永红，姜永正. 显微组织对近α钛合金BT-20疲劳裂纹扩展的影响[J]. 东北大学学报:自然科学版, 2017, 38(3): 345-349.