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Synthesis, structures and properties of liquid-crystalline monomers/polymers containing biphenyl groups
Hu, Jian-She (1); Li, Hao (1); Zhao, Zhan-Xiang (1); Zhang, Bao-Yan (1)
2008, 29 (1):
149-152.
DOI: -
Four LC (liquid-crystalline) monomers (M1-M4) and their corresponding polymers (P1-P4) were synthesized, and their LC structures and properties were characterized with FT-IR, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), polarizing optical microscopy (POM) and X-ray diffraction (XRD). The results showed that M1 and M2 present the enantiotropic nematic phase, M3 presents the nematic phase with SA, SC and SB smectic phases and M4 presents the nematic phase with SA, SC and SB monotropic phases. As to the polymers, P1 and P2 present the nematic phase, P3 and P4 present the SA phase with nematic phase. The melting temperature (tm), glass transition temperature (tg) and clearing point (ti) of monomers/polymers with terminal ethoxyl group are all proved higher than those with terminal ethyl group. Moreover, the monomers/polymers with the flexible spacer group tend to form smectic phase. TGA showed that the polymers P1-P4 all have wide LC temperature ranges and high thermal stability.
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