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Effect of Ni2+ ion content on electromagnetic properties of nanocrystalline NixZn1-xFe2O4 powder
Ma, Rui-Ting (1); Tian, Yan-Wen (1); Zhang, Chun-Li (2); Li, Hong (2)
2008, 29 (3):
358-361.
DOI: -
The spinel-type nanocrystalline nickel-zinc ferrite powder (NixZn1-xFe2O4, where x = 0, 0.2, 0.5, 0.8 and 1) was synthesized by polyacrylamide gel method with acrylamide as monomer and N, N'-Methylenediacrylamide as lattice agent. FT-IR, XRD, TEM and waveguide were used to characterize the composition and morpholopy of the powder. The results showed that both the lattice constant and electromagnetic properties highly depends on Ni2+ content and a 60 cm-1 blue shift of the characteristic absorption peaks of M-O (metal and oxygen) ion bonds comes to pass with increasing Ni2+ content as shown in FT-IR spectra and, as shown in TEM images, the average particles size of the NixZn1-xFe2O4 changes little with x value, i.e., the size is 12, 17 and 15 nm when x is 0, 0.5 and 1, respectively. And the lattice constant decreases to 0.8327 nm from 0.8456 nm as calculated from XRD patterns. In addition, both the dielectric loss (tan Ε) and magnetic loss (tan μ) of the nanocrystalline NixZn1-xFe2O4 increase obviously with increasing Ni2+ content within the tasting frequency range.
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