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Synthesizing sulphides by temperature gradient method
Liu, Tao (1); Yu, Jing-Kun (1); Yuan, Yu-Hao (1)
2005, 26 (3):
260-262.
DOI: -
MgS, TiS2, ZrS2 and WS2 were synthesized by temperature gradient method using Mg, Ti, Zr, W and sublimed sulfur as raw materials. The mineral compositions of the synthesized sulfides as above were determined by X-ray diffraction. Relationships among the evaporating loss of sublimed sulfur and such parameters as volumetric size, synthesizing temperature and compression strength of the synthesized sulfides were studied. The results showed that the maximal evaporating loss of sublimed sulfur is 1.15 g in the synthesizing process under the same experimental conditions. Then, based on the evaporating loss of sublimed sulfur, the temperature gradient and heating rate in the synthesizing process were controlled, to synthesize safely large quantities of MgS, TiS2, ZrS2 and WS2 with their masses up to 56.37 g, 112.00 g, 155.36 g and 247.97 g respectively.
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