Study on CO2 Sorption-Enhanced Steam Reforming of Bio-oil Model for Hydrogen Production
YU Qing-bo, YAO Xin, WU Tian-wei, XIE Hua-qing
2016, 37 (7):
956-959.
DOI: 10.12068/j.issn.1005-3026.2016.07.010
With Ce-Ni/Co as reforming catalyst and CaO from calcination of calcium acetate as CO2 adsorbent, the sorption-enhanced steam reforming of bio-oil for hydrogen production was studied. The results show that the addition of CO2 sorbent can effectively promote the hydrogen molar fraction and hydrogen yield compared with the case without CO2 sorbent under the same temperature and M(S)/ M (C) ratio (the molar mass of steam to carbon in the model compounds of bio-oil ). When the CO2 sorbent existed, the hydrogen molar fraction and yield increased first,then decreased with the increase of the reforming temperature, and reached the maximum at 700℃. With the increase of M(S)/M(C) ratio, the hydrogen molar fraction increased first,then decreased, and was the largest at the M(S)/M(C) ratio of 9,while the hydrogen yield increased till the M(S)/M(C) ratio reached 9, then changed slightly. With the increase of M(CaO)/M(C) ratio ( the molar mass of calcium oxide to carbon in the model compounds of bio-oil), the hydrogen molar fraction increased gradually, but changed slightly after the M(CaO)/M(C) ratio reached 3, while the hydrogen yield increased first and then decreased, reached the maximum at the M(CaO)/M(C) ratio of 3. The optimum conditions for steam reforming of bio-oil with CO2 sorption are 700℃, M(S)/M(C)=9 and M(CaO)/M(C)=3, where the hydrogen molar fraction and the hydrogen yield are 92.2% and 84.1% respectively.
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